Chapter 4: Problem 54
Describe how you would prepare \(250 \mathrm{~mL}\) of a \(0.707 M \mathrm{NaNO}_{3}\) solution.
Chapter 4: Problem 54
Describe how you would prepare \(250 \mathrm{~mL}\) of a \(0.707 M \mathrm{NaNO}_{3}\) solution.
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Predict and explain which of the following systems are electrically conducting: (a) solid \(\mathrm{NaCl}\), (b) molten \(\mathrm{NaCl}\), (c) an aqueous solution of \(\mathrm{NaCl}\)
Calculate the volume in \(\mathrm{mL}\) of a \(1.420 \mathrm{M} \mathrm{NaOH}\) solution required to titrate the following solutions: (a) \(25.00 \mathrm{~mL}\) of a \(2.430 \mathrm{M} \mathrm{HCl}\) solution (b) \(25.00 \mathrm{~mL}\) of a \(4.500 \mathrm{M} \mathrm{H}_{2} \mathrm{SO}_{4}\) solution (c) \(25.00 \mathrm{~mL}\) of a \(1.500 \mathrm{M} \mathrm{H}_{3} \mathrm{PO}_{4}\) solution
Arrange the following species in order of increasing oxidation number of the sulfur atom: (a) \(\mathrm{H}_{2} \mathrm{~S}\) (b) \(\mathrm{S}_{8}\) (c) \(\mathrm{H}_{2} \mathrm{SO}_{4}\) (d) \(\mathrm{S}^{2-},(\mathrm{e}) \mathrm{HS}^{-},(\mathrm{f}) \mathrm{SO}_{2},(\mathrm{~g}) \mathrm{SO}_{3}\)
Hydrogen halides (HF, HCl, HBr, HI) are highly reactive compounds that have many industrial and laboratory uses. (a) In the laboratory, HF and HCl can be generated by reacting \(\mathrm{CaF}_{2}\) and \(\mathrm{NaCl}\) with concentrated sulfuric acid. Write appropriate equations for the reactions. (Hint: These are not redox reactions.) (b) Why is it that HBr and HI cannot be prepared similarly, that is, by reacting \(\mathrm{NaBr}\) and \(\mathrm{NaI}\) with concentrated sulfuric acid? (Hint: \(\mathrm{H}_{2} \mathrm{SO}_{4}\) is a stronger oxidizing agent than both \(\mathrm{Br}_{2}\) and \(\mathrm{I}_{2} .\) ) (c) \(\mathrm{HBr}\) can be prepared by reacting phosphorus tribromide \(\left(\mathrm{PBr}_{3}\right)\) with water. Write an equation for this reaction.
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