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A student placed \(1 \mathrm{~g}\) of each of three compounds \(\mathrm{A}\) \(\mathrm{B},\) and \(\mathrm{C}\) in a container and found that after 1 week no change had occurred. Offer some possible explanations for the fact that no reactions took place. Assume that \(\mathrm{A}, \mathrm{B},\) and \(\mathrm{C}\) are totally miscible liquids.

Short Answer

Expert verified
Possible explanations for no reaction taking place might be the high chemical stability of the compounds A, B, and C, non-conducive conditions for reactions within the container such as temperature or pressure, absence of a necessary catalyst or inadequate concentration of the compounds.

Step by step solution

01

Understand the Concept of a Chemical Reaction

A chemical reaction occurs when substance A reacts with substance B to form a new substance C, or when a single compound breaks down into two or more substances. For a reaction to occur, the reactants must come into direct chemical contact with each other. The rate at which a reaction proceeds can be influenced by several factors such as the presence of a catalyst, concentration of reactants, temperature, and pressure.
02

Analyze Given Compounds A, B and C

Given the fact that no reaction occurred, it can be hypothesized that either the conditions necessitating a reaction were missing, or that the three compounds are inert or stable and do not easily undergo reactions.
03

Possible Reasons for No Reaction

One possible reason that no reaction occurred could be that all compounds A, B and C are chemically stable and do not easily react with other substances. Another possible explanation is that the conditions in the container (e.g., temperature, pressure) were not conducive to facilitating a reaction between the compounds. It is also possible that a catalyst was required to trigger the reaction, but it was missing. The concentration of the compounds could also have been too low to initiate a reaction.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Chemical Stability
Chemical stability refers to the resistance of a substance to change its chemical structure or composition. When a compound is chemically stable, it means it doesn't easily react with other substances. This concept is important because chemical reactions require compounds to interact at the molecular level, breaking and forming bonds. If substances A, B, and C in our exercise are chemically stable, they may not have the tendency or potential to react with each other even if they are mixed together.

Here are some factors that contribute to chemical stability:
  • Strong Chemical Bonds: Compounds with strong bonds require more energy to break and therefore are more stable.
  • Noble Gas Configuration: Stability is often observed in substances that mimic the electron configuration of noble gases, completing their valence shell.
  • Electronegativity: Stability can depend on the attraction of electrons to an atom, preventing reaction with other substances.
This could explain why even after a week, A, B, and C showed no change; their stability prevented any reaction from occurring.
Catalyst
A catalyst is a substance that increases the rate of a chemical reaction without being consumed in the process. In many chemical reactions, even when all the necessary reactants are present, the reaction can still occur very slowly or even not at all without a catalyst. Catalysts work by providing an alternative pathway for the reaction with a lower activation energy. This means that fewer collisions between reactant molecules are needed to start the reaction.

Catalysts can take different forms, including:
  • Homogeneous Catalysts: These are in the same phase as the reactants and often involve solutions.
  • Heterogeneous Catalysts: These exist in a different phase, commonly solid catalysts used in gas or liquid reactions.
In our scenario, the compounds A, B, and C might have required a catalyst to begin reacting with each other. Without this catalyst, the reaction remained inactive for the entire week.
Reaction Conditions
Reaction conditions are the specific physical and environmental factors required to enable or optimize a chemical reaction. These conditions include aspects like temperature, pressure, and concentration, all of which can significantly influence whether or not a reaction occurs and how fast it proceeds. If the conditions are not favorable, even reactive compounds may not interact with each other.

Key reaction conditions to consider include:
  • Temperature: Reactions generally speed up with increased temperature due to particles moving faster and colliding more often.
  • Pressure: Especially important in gases, high pressure can bring molecules closer together, increasing the likelihood of reactions.
  • Concentration: Higher concentration means more particles are present to react, enhancing the rate of reaction.
In the context of the exercise, it is possible that the reaction conditions weren't suitable—perhaps the temperature was too low, or the pressure too relaxed for A, B, and C to react, resulting in their inert behavior over the observed week.

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Most popular questions from this chapter

Consider the following reaction at \(25^{\circ} \mathrm{C}\) : $$ \mathrm{Fe}(\mathrm{OH})_{2}(s) \rightleftharpoons \mathrm{Fe}^{2+}(a q)+2 \mathrm{OH}^{-}(a q) $$ Calculate \(\Delta G^{\circ}\) for the reaction. \(K_{\mathrm{sp}}\) for \(\mathrm{Fe}(\mathrm{OH})_{2}\) is \(1.6 \times 10^{-14}\).

For each pair of substances listed here, choose the one having the larger standard entropy value at \(25^{\circ} \mathrm{C}\). The same molar amount is used in the comparison. Explain the basis for your choice. (a) \(\operatorname{Li}(s)\) or \(\operatorname{Li}(l)\) (b) \(\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(l)\) or \(\mathrm{CH}_{3} \mathrm{OCH}_{3}(l)\) (c) \(\operatorname{Ar}(g)\) or \(\operatorname{Xe}(g)\) (d) \(\mathrm{CO}(g)\) or \(\mathrm{CO}_{2}(g)\) (e) \(\mathrm{O}_{2}(g)\) or \(\mathrm{O}_{3}(g)\) (f) \(\mathrm{NO}_{2}(g)\) or \(\mathrm{N}_{2} \mathrm{O}_{4}(g)\)

In the Mond process for the purification of nickel, carbon monoxide is reacted with heated nickel to produce \(\mathrm{Ni}(\mathrm{CO})_{4},\) which is a gas and can therefore be separated from solid impurities: $$ \mathrm{Ni}(s)+4 \mathrm{CO}(g) \rightleftharpoons \mathrm{Ni}(\mathrm{CO})_{4}(g) $$ Given that the standard free energies of formation of \(\mathrm{CO}(g)\) and \(\mathrm{Ni}(\mathrm{CO})_{4}(g)\) are \(-137.3 \mathrm{~kJ} / \mathrm{mol}\) and \(-587.4 \mathrm{~kJ} / \mathrm{mol}\), respectively, calculate the equilibrium constant of the reaction at \(80^{\circ} \mathrm{C}\). Assume that \(\Delta G_{f}^{\circ}\) is temperature independent.

Under what conditions does a substance have a standard entropy of zero? Can a substance ever have a negative standard entropy?

(a) Calculate \(\Delta G^{\circ}\) and \(K_{P}\) for the following equilibrium reaction at \(25^{\circ} \mathrm{C}\). The \(\Delta G_{f}^{\circ}\) values are 0 for \(\mathrm{Cl}_{2}(g),-286 \mathrm{~kJ} / \mathrm{mol}\) for \(\mathrm{PCl}_{3}(g),\) and \(-325 \mathrm{~kJ} / \mathrm{mol}\) for \(\mathrm{PCl}_{5}(g)\) $$ \mathrm{PCl}_{5}(g) \rightleftharpoons \mathrm{PCl}_{3}(g)+\mathrm{Cl}_{2}(g) $$. (b) Calculate \(\Delta G\) for the reaction if the partial pressures of the initial mixture are \(P_{\mathrm{PCl}_{5}}=0.0029 \mathrm{~atm}\) \(P_{\mathrm{PCl}_{3}}=0.27 \mathrm{~atm},\) and \(P_{\mathrm{Cl}_{2}}=0.40 \mathrm{~atm}\).

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