Chapter 17: Problem 45
How many grams of \(\mathrm{CaCO}_{3}\) will dissolve in \(3.0 \times\) \(10^{2} \mathrm{~mL}\) of \(0.050 \mathrm{M} \mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2} ?\)
Chapter 17: Problem 45
How many grams of \(\mathrm{CaCO}_{3}\) will dissolve in \(3.0 \times\) \(10^{2} \mathrm{~mL}\) of \(0.050 \mathrm{M} \mathrm{Ca}\left(\mathrm{NO}_{3}\right)_{2} ?\)
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Get started for freeWrite the solubility product expression for the ionic compound \(\mathrm{A}_{x} \mathrm{~B}_{y}\).
Radiochemical techniques are useful in estimating the solubility product of many compounds. In one experiment, \(50.0 \mathrm{~mL}\) of a \(0.010 \mathrm{MAgNO}_{3}\) solution containing a silver isotope with a radioactivity of 74,025 counts per min per \(\mathrm{mL}\) were mixed with \(100 \mathrm{~mL}\) of a \(0.030 \mathrm{M} \mathrm{NaIO}_{3}\) solution. The mixed solution was diluted to \(500 \mathrm{~mL}\) and filtered to remove all of the \(\mathrm{AgIO}_{3}\) precipitate. The remaining solution was found to have a radioactivity of 44.4 counts per min per \(\mathrm{mL}\). What is the \(K_{\mathrm{sp}}\) of \(\mathrm{AgIO}_{3} ?\)
The \(\mathrm{p} K_{\mathrm{a}}\) of the indicator methyl orange is \(3.46 .\) Over what pH range does this indicator change from \(90 \%\) HIn to \(90 \% \mathrm{In}^{-} ?\)
For which of these reactions is the equilibrium constant called a solubility product? (a) \(\mathrm{Zn}(\mathrm{OH})_{2}(s)+2 \mathrm{OH}^{-}(a q) \rightleftharpoons \mathrm{Zn}(\mathrm{OH})_{4}^{2-}(a q)\) (b) \(3 \mathrm{Ca}^{2+}(a q)+2 \mathrm{PO}_{4}^{3-}(a q) \rightleftharpoons \mathrm{Ca}_{3}\left(\mathrm{PO}_{4}\right)_{2}(s)\) (c) \(\mathrm{CaCO}_{3}(s)+2 \mathrm{H}^{+}(a q) \rightleftharpoons\) \(\mathrm{Ca}^{2+}(a q)+\mathrm{H}_{2} \mathrm{O}(l)+\mathrm{CO}_{2}(g)\) (d) \(\mathrm{PbI}_{2}(s) \rightleftharpoons \mathrm{Pb}^{2+}(a q)+2 \mathrm{I}^{-}(a q)\)
Acid-base reactions usually go to completion. Confirm this statement by calculating the equilibrium constant for each of the following cases: (a) a strong acid reacting with a strong base, (b) a strong acid reacting with a weak base \(\left(\mathrm{NH}_{3}\right),\) (c) a weak acid \(\left(\mathrm{CH}_{3} \mathrm{COOH}\right)\) reacting with a strong base, \((\mathrm{d})\) a weak acid \(\left(\mathrm{CH}_{3} \mathrm{COOH}\right)\) reacting with a weak base \(\left(\mathrm{NH}_{3}\right)\) (Hint: Strong acids exist as \(\mathrm{H}^{+}\) ions and strong bases exist as \(\mathrm{OH}^{-}\) ions in solution. You need to look up the \(K_{\mathrm{a}}, K_{\mathrm{b}}\), and \(K_{\mathrm{w}}\) values.)
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