Chapter 17: Problem 1
Define buffer solution.
Short Answer
Step by step solution
Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 17: Problem 1
Define buffer solution.
These are the key concepts you need to understand to accurately answer the question.
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The \(\mathrm{p} K_{\mathrm{a}}\) of the indicator methyl orange is \(3.46 .\) Over what pH range does this indicator change from \(90 \%\) HIn to \(90 \% \mathrm{In}^{-} ?\)
The maximum allowable concentration of \(\mathrm{Pb}^{2+}\) ions in drinking water is \(0.05 \mathrm{ppm}\) (that is, \(0.05 \mathrm{~g}\) of \(\mathrm{Pb}^{2+}\) in 1 million g of water). Is this guideline exceeded if an underground water supply is at equilibrium with the mineral anglesite, \(\mathrm{PbSO}_{4}\left(K_{\mathrm{sp}}=1.6 \times 10^{-8}\right) ?\)
\(\mathrm{CaSO}_{4}\left(K_{\mathrm{sp}}=2.4 \times 10^{-5}\right)\) has a larger \(K_{\mathrm{sp}}\) value than that of \(\mathrm{Ag}_{2} \mathrm{SO}_{4}\left(K_{\mathrm{sp}}=1.4 \times 10^{-5}\right)\). Does it fol- low that \(\mathrm{CaSO}_{4}\) also has greater solubility \((\mathrm{g} / \mathrm{L}) ?\)
Calculate the \(\mathrm{pH}\) of these two buffer solutions: (a) \(2.0 \mathrm{M} \mathrm{CH}_{3} \mathrm{COONa} / 2.0 \mathrm{MCH}_{3} \mathrm{COOH}\), (b) \(0.20 \mathrm{M}\) \(\mathrm{CH}_{3} \mathrm{COONa} / 0.20 \mathrm{M} \mathrm{CH}_{3} \mathrm{COOH}\). Which is the more effective buffer? Why?
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