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Eggshells are composed mostly of calcium carbonate \(\left(\mathrm{CaCO}_{3}\right)\) formed by the reaction $$ \mathrm{Ca}^{2+}(a q)+\mathrm{CO}_{3}^{2-}(a q) \rightleftharpoons \mathrm{CaCO}_{3}(s) $$ The carbonate ions are supplied by carbon dioxide produced as a result of metabolism. Explain why eggshells are thinner in the summer, when the rate of chicken panting is greater. Suggest a remedy for this situation.

Short Answer

Expert verified
Eggshells are thinner in the summer because increased chicken panting excretes more carbon dioxide, reducing the availability of carbonate ions for the calcium carbonate \(\mathrm{CaCO}_{3}\) eggshell formation. To remedy this, chickens can be kept cool and given a calcium-rich diet.

Step by step solution

01

Understand the chemical equation

The equation describes how calcium ions \(\mathrm{Ca}^{2+}\) react with carbonate ions \(\mathrm{CO}_{3}^{2-}\) to form calcium carbonate \(\mathrm{CaCO}_{3}\), the main substance in eggshells. This reaction is reversible, meaning it can proceed in both directions.
02

Connect panting to eggshell formation

When chickens pant, they exhale more carbon dioxide (CO2), which is the source of the carbonate ions in the eggshell formation reaction. Thus, increased panting can deplete carbonate ions and reduce the production of calcium carbonate \(\mathrm{CaCO}_{3}\), resulting in thinner eggshells.
03

Suggest a remedy

One possible remedy is to ensure that chickens are kept cool during the summer, with methods such as providing shade or using fans. Furthermore, providing a diet rich in calcium can also help with eggshell formation, as it could help make up for the reduced carbonate ion concentration.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Calcium Carbonate
Calcium carbonate is a compound with the chemical formula \(\mathrm{CaCO}_{3}\). It forms the primary structure of eggshells, providing strength and protection for the developing chick inside the egg. This compound is created through the chemical reaction between calcium ions \(\mathrm{Ca}^{2+}\) and carbonate ions \(\mathrm{CO}_{3}^{2-}\). The equation for this reaction is:\[\mathrm{Ca}^{2+}(aq) + \mathrm{CO}_{3}^{2-}(aq) \rightleftharpoons \mathrm{CaCO}_{3}(s)\]This equation reveals that the reaction can move both forward, creating solid calcium carbonate, or backward, breaking it down into its ionic components.
The balance between these processes is crucial for eggshell formation. Calcium carbonate not only contributes to the rigidity of the eggshell but also acts as a significant mineral source for the growing embryo. The understanding of this chemical equilibrium helps us in exploring the mechanisms of eggshell formation further, especially under varying conditions such as temperature changes.
Chicken Panting
Chickens, like many animals, pant as a means to regulate their body temperature, especially during hot weather. Panting increases the rate of respiration, leading to the rapid exhalation of carbon dioxide. In the context of eggshell formation, this process has a significant impact.
When chickens pant more vigorously, they lose more carbon dioxide from their bodies. Carbon dioxide is vital for the production of carbonate ions \(\mathrm{CO}_{3}^{2-}\), which are necessary for the synthesis of calcium carbonate in eggshells. With decreased levels of carbon dioxide, fewer carbonate ions are available, disrupting the equilibrium of the chemical reaction that forms \(\mathrm{CaCO}_{3}\).
  • Panting can result in a decrease in the formation of calcium carbonate.
  • This leads to thinner eggshells due to compromised supply of carbonate ions.
Understanding the relationship between panting and eggshell formation enables farmers to implement strategies to mitigate these effects, such as maintaining a cooler environment for the chickens.
Eggshell Formation
Eggshell formation is a fascinating process that relies heavily on the availability of calcium carbonate. The process begins within the hen’s reproductive system, where calcium ions and carbonate ions meet to form the shells around developing eggs. This intricate balance is controlled by metabolic processes and environmental factors, like temperature.
During hot summers, chickens are prone to pant more to cool down, which affects the levels of carbon dioxide in the blood and consequently the availability of carbonate ions. This impacts the formation of strong and thick eggshells. To counteract the challenges presented by increased panting:
  • Provide plenty of shade and cooling fans to reduce panting and conserve CO2 levels.
  • Ensure a diet rich in calcium to compensate for the reduced availability of carbonate ions.
These solutions can help in maintaining the optimum conditions for eggshell production, ensuring the laid eggs are protected and viable for hatching.

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Most popular questions from this chapter

Briefly describe the importance of equilibrium in the study of chemical reactions.

A mixture containing 3.9 moles of \(\mathrm{NO}\) and 0.88 mole of \(\mathrm{CO}_{2}\) was allowed to react in a flask at a certain temperature according to the equation $$ \mathrm{NO}(g)+\mathrm{CO}_{2}(g) \rightleftharpoons \mathrm{NO}_{2}(g)+\mathrm{CO}(g) $$ At equilibrium, 0.11 mole of \(\mathrm{CO}_{2}\) was present. Calculate the equilibrium constant \(K_{\mathrm{c}}\) of this reaction.

Write equilibrium constant expressions for \(K_{\mathrm{c}}\) and for \(K_{P}\), if applicable, for these processes: (a) \(2 \mathrm{CO}_{2}(g) \rightleftharpoons 2 \mathrm{CO}(g)+\mathrm{O}_{2}(g)\) (b) \(3 \mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{O}_{3}(g)\) (c) \(\mathrm{CO}(g)+\mathrm{Cl}_{2}(g) \rightleftharpoons \mathrm{COCl}_{2}(g)\) (d) \(\mathrm{H}_{2} \mathrm{O}(g)+\mathrm{C}(s) \rightleftharpoons \mathrm{CO}(g)+\mathrm{H}_{2}(g)\) (e) \(\mathrm{HCOOH}(a q) \rightleftharpoons \mathrm{H}^{+}(a q)+\mathrm{HCOO}^{-}(a q)\) (f) \(2 \mathrm{HgO}(s) \rightleftharpoons 2 \mathrm{Hg}(l)+\mathrm{O}_{2}(g)\)

Photosynthesis can be represented by $$ \begin{array}{r} 6 \mathrm{CO}_{2}(g)+6 \mathrm{H}_{2} \mathrm{O}(l) \rightleftharpoons \mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(s)+6 \mathrm{O}_{2}(g) \\ \Delta H^{\circ}=2801 \mathrm{~kJ} / \mathrm{mol} \end{array} $$ Explain how the equilibrium would be affected by the following changes: (a) partial pressure of \(\mathrm{CO}_{2}\) is increased, (b) \(\mathrm{O}_{2}\) is removed from the mixture, (c) \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\) (sucrose) is removed from the mixture, (d) more water is added, (e) a catalyst is added, (f) temperature is decreased, (g) more sunlight falls on the plants.

Consider the reaction in a closed container: $$ \mathrm{N}_{2} \mathrm{O}_{4}(g) \rightleftharpoons 2 \mathrm{NO}_{2}(g) $$ Initially, 1 mole of \(\mathrm{N}_{2} \mathrm{O}_{4}\) is present. At equilibrium, \(\alpha\) mole of \(\mathrm{N}_{2} \mathrm{O}_{4}\) has dissociated to form \(\mathrm{NO}_{2}\). (a) Derive an expression for \(K_{P}\) in terms of \(\alpha\) and \(P,\) the total pressure. (b) How does the expression in (a) help you predict the shift in equilibrium caused by an increase in \(P ?\) Does your prediction agree with Le Châtelier's principle?

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