Chapter 15: Problem 3
Briefly describe the importance of equilibrium in the study of chemical reactions.
Chapter 15: Problem 3
Briefly describe the importance of equilibrium in the study of chemical reactions.
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Get started for freeConsider the equilibrium $$ 2 \mathrm{NOBr}(g) \rightleftharpoons 2 \mathrm{NO}(g)+\mathrm{Br}_{2}(g) $$ If nitrosyl bromide, NOBr, is 34 percent dissociated at \(25^{\circ} \mathrm{C}\) and the total pressure is \(0.25 \mathrm{~atm},\) calculate \(K_{P}\) and \(K_{\mathrm{c}}\) for the dissociation at this temperature.
For the reaction $$ \mathrm{H}_{2}(g)+\mathrm{CO}_{2}(g) \rightleftharpoons \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{CO}(g) $$ at \(700^{\circ} \mathrm{C}, K_{\mathrm{c}}=0.534 .\) Calculate the number of moles of \(\mathrm{H}_{2}\) formed at equilibrium if a mixture of 0.300 mole of \(\mathrm{CO}\) and 0.300 mole of \(\mathrm{H}_{2} \mathrm{O}\) is heated to \(700^{\circ} \mathrm{C}\) in a 10.0 - \(\mathrm{L}\) container.
The vapor pressure of mercury is \(0.0020 \mathrm{mmHg}\) at \(26^{\circ} \mathrm{C}\). (a) Calculate \(K_{\mathrm{c}}\) and \(K_{P}\) for the process \(\mathrm{Hg}(l) \rightleftharpoons \mathrm{Hg}(g) .\) (b) A chemist breaks a thermometer and spills mercury onto the floor of a laboratory measuring \(6.1 \mathrm{~m}\) long, \(5.3 \mathrm{~m}\) wide, and \(3.1 \mathrm{~m}\) high. Calculate the mass of mercury (in grams) vaporized at equilibrium and the concentration of mercury vapor in \(\mathrm{mg} / \mathrm{m}^{3}\). Does this concentration exceed the safety limit of \(0.050 \mathrm{mg} / \mathrm{m}^{3} ?\) (Ignore the volume of furniture and other objects in the laboratory.)
Baking soda (sodium bicarbonate) undergoes thermal decomposition as $$ 2 \mathrm{NaHCO}_{3}(s) \rightleftharpoons \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ Would we obtain more \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\) by adding extra baking soda to the reaction mixture in (a) a closed vessel or (b) an open vessel?
What effect does an increase in pressure have on each of these systems at equilibrium? (a) \(\mathrm{A}(s) \rightleftharpoons 2 \mathrm{~B}(s)\) (b) \(2 \mathrm{~A}(l) \rightleftharpoons \mathrm{B}(l)\) (c) \(\mathrm{A}(s) \rightleftharpoons \mathrm{B}(g)\) (d) \(\mathrm{A}(g) \rightleftharpoons \mathrm{B}(g)\) (e) \(\mathrm{A}(g) \rightleftharpoons 2 \mathrm{~B}(g)\) The temperature is kept constant. In each case, the reacting mixture is in a cylinder fitted with a movable piston.
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