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Briefly describe the importance of equilibrium in the study of chemical reactions.

Short Answer

Expert verified
Equilibrium in chemistry refers to the state when rates of forward and reverse reactions are equal, leading to no overall net effect. It's crucial in studying chemical reactions because it lets us predict the concentration of reactants and products at any point in a reaction, allowing us to manipulate a reaction's conditions to get a desired result. In addition, it helps us understand why some reactions do not go to completion, and an equilibrium state still exists.

Step by step solution

01

Define Equilibrium

In the context of chemistry, equilibrium refers to the state where the forward and reverse reactions occur at the same rate, leading to no overall net effect. It does not necessarily mean that the reactants and products are equal in quantity, but that their ratios stay constant.
02

Explain the Occurrence of Equilibrium in Reactions

Equilibrium occurs in a chemical reaction when the rate of reaction in forward direction equals the rate of reverse reaction. It means that the reactants react to form the products, and the products decompose to form the reactants at the same rate.
03

Discuss the Importance of Equilibrium in the Study of Chemical Reactions

Understanding equilibrium is essential in the study of chemical reactions because it allows us to predict the concentrations of reactants and products at any given time in a reaction. This understanding can be used to manipulate conditions of a reaction to get the desired result. For example, to maximise product output in industrial reactions. Additionally, some reactions do not go to completion, and equilibrium will still exist – an understanding of that allows us to make sense of why that happens.

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Most popular questions from this chapter

Consider the equilibrium $$ 2 \mathrm{NOBr}(g) \rightleftharpoons 2 \mathrm{NO}(g)+\mathrm{Br}_{2}(g) $$ If nitrosyl bromide, NOBr, is 34 percent dissociated at \(25^{\circ} \mathrm{C}\) and the total pressure is \(0.25 \mathrm{~atm},\) calculate \(K_{P}\) and \(K_{\mathrm{c}}\) for the dissociation at this temperature.

For the reaction $$ \mathrm{H}_{2}(g)+\mathrm{CO}_{2}(g) \rightleftharpoons \mathrm{H}_{2} \mathrm{O}(g)+\mathrm{CO}(g) $$ at \(700^{\circ} \mathrm{C}, K_{\mathrm{c}}=0.534 .\) Calculate the number of moles of \(\mathrm{H}_{2}\) formed at equilibrium if a mixture of 0.300 mole of \(\mathrm{CO}\) and 0.300 mole of \(\mathrm{H}_{2} \mathrm{O}\) is heated to \(700^{\circ} \mathrm{C}\) in a 10.0 - \(\mathrm{L}\) container.

The vapor pressure of mercury is \(0.0020 \mathrm{mmHg}\) at \(26^{\circ} \mathrm{C}\). (a) Calculate \(K_{\mathrm{c}}\) and \(K_{P}\) for the process \(\mathrm{Hg}(l) \rightleftharpoons \mathrm{Hg}(g) .\) (b) A chemist breaks a thermometer and spills mercury onto the floor of a laboratory measuring \(6.1 \mathrm{~m}\) long, \(5.3 \mathrm{~m}\) wide, and \(3.1 \mathrm{~m}\) high. Calculate the mass of mercury (in grams) vaporized at equilibrium and the concentration of mercury vapor in \(\mathrm{mg} / \mathrm{m}^{3}\). Does this concentration exceed the safety limit of \(0.050 \mathrm{mg} / \mathrm{m}^{3} ?\) (Ignore the volume of furniture and other objects in the laboratory.)

Baking soda (sodium bicarbonate) undergoes thermal decomposition as $$ 2 \mathrm{NaHCO}_{3}(s) \rightleftharpoons \mathrm{Na}_{2} \mathrm{CO}_{3}(s)+\mathrm{CO}_{2}(g)+\mathrm{H}_{2} \mathrm{O}(g) $$ Would we obtain more \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}\) by adding extra baking soda to the reaction mixture in (a) a closed vessel or (b) an open vessel?

What effect does an increase in pressure have on each of these systems at equilibrium? (a) \(\mathrm{A}(s) \rightleftharpoons 2 \mathrm{~B}(s)\) (b) \(2 \mathrm{~A}(l) \rightleftharpoons \mathrm{B}(l)\) (c) \(\mathrm{A}(s) \rightleftharpoons \mathrm{B}(g)\) (d) \(\mathrm{A}(g) \rightleftharpoons \mathrm{B}(g)\) (e) \(\mathrm{A}(g) \rightleftharpoons 2 \mathrm{~B}(g)\) The temperature is kept constant. In each case, the reacting mixture is in a cylinder fitted with a movable piston.

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