Chapter 14: Problem 28
Write the Arrhenius equation and define all terms.
Chapter 14: Problem 28
Write the Arrhenius equation and define all terms.
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Consider the zero-order reaction \(\mathrm{A} \longrightarrow\) product. (a) Write the rate law for the reaction. (b) What are the units for the rate constant? (c) Plot the rate of the reaction versus [A].
A flask contains a mixture of compounds \(A\) and \(B\). Both compounds decompose by first-order kinetics. The half-lives are 50.0 min for \(A\) and 18.0 min for \(B\). If the concentrations of \(\mathrm{A}\) and \(\mathrm{B}\) are equal initially, how long will it take for the concentration of \(\mathrm{A}\) to be four times that of \(\mathrm{B} ?\)
Variation of the rate constant with temperature for the first-order reaction $$ 2 \mathrm{~N}_{2} \mathrm{O}_{5}(g) \longrightarrow 2 \mathrm{~N}_{2} \mathrm{O}_{4}(g)+\mathrm{O}_{2}(g) $$ is given in the following table. Determine graphically the activation energy for the reaction. $$ \begin{array}{lc} \mathrm{T}(\mathrm{K}) & \mathrm{k}\left(\mathrm{s}^{-1}\right) \\ \hline 273 & 7.87 \times 10^{3} \\ 298 & 3.46 \times 10^{5} \\ 318 & 4.98 \times 10^{6} \\ 338 & 4.87 \times 10^{7} \end{array} $$
A quantity of \(6 \mathrm{~g}\) of granulated \(\mathrm{Zn}\) is added to a solution of \(2 M \mathrm{HCl}\) in a beaker at room temperature. Hydrogen gas is generated. For each of the following changes (at constant volume of the acid) state whether the rate of hydrogen gas evolution will be increased, decreased, or unchanged: (a) \(6 \mathrm{~g}\) of powdered \(\mathrm{Zn}\) is used; \((\mathrm{b}) 4 \mathrm{~g}\) of granulated \(\mathrm{Zn}\) is used; \((\mathrm{c})\) \(2 M\) acetic acid is used instead of \(2 M \mathrm{HCl} ;\) d) temperature is raised to \(40^{\circ} \mathrm{C}\).
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