Chapter 14: Problem 102
A factory that specializes in the refinement of transition metals such as titanium was on fire. The firefighters were advised not to douse the fire with water. Why?
Chapter 14: Problem 102
A factory that specializes in the refinement of transition metals such as titanium was on fire. The firefighters were advised not to douse the fire with water. Why?
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The concentrations of enzymes in cells are usually quite small. What is the biological significance of this fact?
A certain first-order reaction is 35.5 percent complete in 4.90 min at \(25^{\circ} \mathrm{C}\). What is its rate constant?
In a certain industrial process using a heterogeneous catalyst, the volume of the catalyst (in the shape of a sphere) is \(10.0 \mathrm{~cm}^{3}\). Calculate the surface area of the catalyst. If the sphere is broken down into eight spheres, each of which has a volume of \(1.25 \mathrm{~cm}^{3}\), what is the total surface area of the spheres? Which of the two geometric configurations of the catalyst is more effective? Explain. (The surface area of a sphere is \(4 \pi r^{2},\) in which \(r\) is the radius of the sphere.)
The rate constant for the second-order reaction $$ 2 \mathrm{NO}_{2}(g) \longrightarrow 2 \mathrm{NO}(g)+\mathrm{O}_{2}(g) $$ is \(0.54 / M \cdot \mathrm{s}\) at \(300^{\circ} \mathrm{C}\). (a) How long (in seconds) would it take for the concentration of \(\mathrm{NO}_{2}\) to decrease from \(0.62 M\) to \(0.28 M ?\) (b) Calculate the half-lives at these two concentrations.
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