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What is meant by the rate of a chemical reaction?

Short Answer

Expert verified
The rate of a chemical reaction describes the speed at which the reactions or transformations occur. It's quantified by the change in concentration of reactants or products per unit time and can be influenced by factors such as concentration, temperature, pressure, presence of a catalyst, and surface area.

Step by step solution

01

Define a Rate of Reaction

The rate of a reaction refers to the speed at which a chemical reaction takes place. This is generally quantified by the change in concentration of reactants or products per unit time.
02

Explain its Importance in Chemical Reactions

The rate of a chemical reaction is a crucial factor in chemistry. It helps in understanding how quickly a reactant gets converted into a product. For certain reactions, a slow rate might be favorable, while for others a fast rate might be required.
03

Discuss Factors Affecting Rate of Reaction

Multiple factors can affect the rate of a reaction, including: the concentration of reactants, temperature, pressure, presence of a catalyst, and the surface area of solid reactants.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Concentration Changes
In chemistry, the concentration of reactants is a significant player in determining the rate of reaction. The concentration refers to the amount of a substance in a given volume, and changes in concentration can lead to changes in how quickly a reaction takes place.
For example, if you increase the concentration of reactants, there are more particles available to collide and react, typically leading to an increase in the reaction rate. This is because more particles increase the likelihood of collisions that result in reactions.
Conversely, when the concentration decreases, the reaction rate can slow down since there are fewer particles to collide. It's important to understand these changes in concentration to predict how different reaction conditions might affect the speed or progress of a chemical process.
Factors Affecting Reaction Rate
There are several factors that can influence how fast or slow a chemical reaction occurs. Understanding these factors is key to controlling and optimizing reactions for various applications. Here are some common factors that affect reaction rates:
  • Concentration of Reactants: As previously mentioned, higher concentrations generally lead to a faster reaction rate due to an increased number of effective collisions.
  • Temperature: Elevating the temperature often increases reaction rates because it raises the energy of the particles, leading to more frequent and energetic collisions.
  • Pressure: For reactions involving gases, higher pressure can compress the particles closer together, increasing the frequency of collisions.
  • Surface Area: Finely divided or powdered solids react faster than larger chunks because they have more surface area available for collisions.
  • Catalysts: Catalysts are unique substances that accelerate a reaction without being consumed by it, providing a pathway with a lower activation energy.
Each of these factors can be manipulated to control reaction rates, which is especially useful in industrial and laboratory settings.
Catalysts in Chemical Reactions
Catalysts play a fascinating and crucial role in the world of chemical reactions. They are substances that significantly speed up a reaction by lowering the activation energy required for the reactants to transform into products. This means that reactions can occur faster and often at lower temperatures than they would without a catalyst.
Catalysts are not used up or altered during the reaction, which makes them highly efficient and valuable in repeated processes. In many industrial and biological reactions, catalysts are the key to achieving practical reaction rates under reasonable conditions.
Biological catalysts, known as enzymes, are particularly important because they allow vital biochemical reactions to proceed efficiently in living organisms. By offering an alternative reaction pathway, catalysts are indispensable tools for chemists and engineers working to optimize processes.

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Most popular questions from this chapter

The rate of the reaction $$ \begin{aligned} \mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}(a q) &+\mathrm{H}_{2} \mathrm{O}(l) \\ \longrightarrow & \mathrm{CH}_{3} \mathrm{COOH}(a q)+\mathrm{C}_{2} \mathrm{H}_{5} \mathrm{OH}(a q) \end{aligned} $$ shows first-order characteristics-that is, rate \(=\) \(k\left[\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}\right]\) - even though this is a second- order reaction (first order in \(\mathrm{CH}_{3} \mathrm{COOC}_{2} \mathrm{H}_{5}\) and first order in \(\mathrm{H}_{2} \mathrm{O}\) ). Explain.

The thermal decomposition of phosphine \(\left(\mathrm{PH}_{3}\right)\) into phosphorus and molecular hydrogen is a first-order reaction: $$ 4 \mathrm{PH}_{3}(g) \longrightarrow \mathrm{P}_{4}(g)+6 \mathrm{H}_{2}(g) $$ The half-life of the reaction is 35.0 s at \(680^{\circ} \mathrm{C}\). Calculate (a) the first-order rates constant for the reaction and (b) the time required for 95 percent of the phosphine to decompose.

Thallium(I) is oxidized by cerium(IV) as follows: $$ \mathrm{Tl}^{+}+2 \mathrm{Ce}^{4+} \longrightarrow \mathrm{Tl}^{3+}+2 \mathrm{Ce}^{3+} $$ The elementary steps, in the presence of \(\mathrm{Mn}(\mathrm{II}),\) are as follows: $$ \begin{aligned} \mathrm{Ce}^{4+}+\mathrm{Mn}^{2+} & \longrightarrow \mathrm{Ce}^{3+}+\mathrm{Mn}^{3+} \\ \mathrm{Ce}^{4+}+\mathrm{Mn}^{3+} \longrightarrow \mathrm{Ce}^{3+}+\mathrm{Mn}^{4+} \\ \mathrm{Tl}^{+}+\mathrm{Mn}^{4+} \longrightarrow \mathrm{Tl}^{3+}+\mathrm{Mn}^{2+} \end{aligned} $$ (a) Identify the catalyst, intermediates, and the ratedetermining step if the rate law is given by rate \(=\) \(k\left[\mathrm{Ce}^{4+}\right]\left[\mathrm{Mn}^{2+}\right]\) (b) Explain why the reaction is slow without the catalyst. (c) Classify the type of catalysis (homogeneous or heterogeneous).

Consider this elementary step: $$ X+2 Y \longrightarrow X Y_{2} $$ (a) Write a rate law for this reaction. (b) If the initial rate of formation of \(\mathrm{XY}_{2}\) is \(3.8 \times 10^{-3} \mathrm{M} / \mathrm{s}\) and the initial concentrations of \(X\) and \(Y\) are \(0.26 M\) and \(0.88 M\), what is the rate constant of the reaction?

The rate law for this reaction $$ \mathrm{CO}(g)+\mathrm{NO}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+\mathrm{NO}(g) $$ is rate \(=k\left[\mathrm{NO}_{2}\right]^{2}\). Suggest a plausible mechanism for the reaction, given that the unstable species \(\mathrm{NO}_{3}\) is an intermediate.

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