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The greater the molar heat of vaporization of a liquid, the greater its vapor pressure. True or false?

Short Answer

Expert verified
False. The greater the molar heat of vaporization of a liquid, the lower its vapor pressure.

Step by step solution

01

Understanding Molar Heat of Vaporization

Molar heat of vaporization refers to the amount of energy needed to vaporize one mole of a liquid at its boiling point with no change in pressure. It indicates how strong the intermolecular forces of attraction are in a liquid; high molar heat of vaporization means strong forces of attraction and vice versa.
02

Understanding Vapor Pressure

Vapor pressure is defined as the pressure exerted by the vapor in equilibrium with its condensed phases at a particular temperature. In simple terms, it measures the tendency of particles to escape from the liquid (or a solid) state and become vapor. The higher the vapor pressure of a liquid, the faster it evaporates.
03

Relation Between Molar Heat Of Vaporization And Vapor Pressure

The higher the molar heat of vaporization, the more energy is needed to transform the liquid into a gas, indicating stronger intermolecular bonds. Stronger intermolecular bonds mean that less particles will become vapor at a given temperature. Therefore, the vapor pressure decreases with an increase in the molar heat of vaporization.

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