Chapter 10: Problem 27
How does a hybrid orbital differ from a pure atomic orbital? Can two \(2 p\) orbitals of an atom hybridize to give two hybridized orbitals?
Chapter 10: Problem 27
How does a hybrid orbital differ from a pure atomic orbital? Can two \(2 p\) orbitals of an atom hybridize to give two hybridized orbitals?
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Get started for freeAluminum trichloride \(\left(\mathrm{AlCl}_{3}\right)\) is an electron-deficient molecule. It has a tendency to form a dimer (a molecule made of two \(\mathrm{AlCl}_{3}\) units): $$ \mathrm{AlCl}_{3}+\mathrm{AlCl}_{3} \longrightarrow \mathrm{Al}_{2} \mathrm{Cl}_{6} $$ (a) Draw a Lewis structure for the dimer. (b) Describe the hybridization state of \(\mathrm{Al}\) in \(\mathrm{AlCl}_{3}\) and \(\mathrm{Al}_{2} \mathrm{Cl}_{6}\). (c) Sketch the geometry of the dimer. (d) Do these molecules possess a dipole moment?
Predict the geometry of sulfur dichloride \(\left(\mathrm{SCl}_{2}\right)\) and the hybridization of the sulfur atom.
Use molecular orbital theory to compare the relative stabilities of \(\mathrm{F}_{2}\) and \(\mathrm{F}_{2}^{+}\)
How is the geometry of a molecule defined and why is the study of molecular geometry important?
Compare the relative stability of these species and indicate their magnetic properties (that is, diamagnetic or paramagnetic): \(\mathrm{O}_{2}, \mathrm{O}_{2}^{+}, \mathrm{O}_{2}^{-}\) (superoxide ion), \(\mathrm{O}_{2}^{2-}\) (peroxide ion).
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