Question

Draw structural formulas for all the isomers of ${\mathrm{C}}_7{\mathrm{H}}_{16}$.

Short answer

The possible isomers of $C_7{H}_{16}$ include a linear structure (heptane), as well as numerous branched structures.

Step-by-step solution

Drawing linear structure

Begin by drawing the linear structure of heptane. This structure consists of a straight chain of seven carbon atoms, with each carbon atom bonded to as many hydrogen atoms as needed to reach a total of four bonds per carbon.

Drawing branched structures

Next, draw the structures that result from moving a methyl group ($C{H}_3$) from the end of the chain to an internal carbon. Start by moving the methyl group to carbon 2, then to carbon 3, and finally to carbon 4.

Formulating Additional Complex Isomers

For more complex isomers, try incorporating ethyl groups ($C_2{H}_5$) or propyl groups ($C_3{H}_7$) in the structure. This requires shifting around multiple hydrogen atoms and possibly multiple carbon atoms. The possibilities are numerous, and the goal should be a comprehensive set of possible structures. It is important to check each structure to make sure that it doesn't resemble any previously drawn structures, and each carbon atom should have four bonds.

Key concepts

Structural formulas

Structural formulas are specific ways to represent the structures of molecules using symbols for elements and lines to show chemical bonds. For carbon-based compounds, such as hydrocarbons, the carbon atoms are represented by the letter 'C', and the hydrogen atoms by 'H'.

• The lines connecting the atoms signify chemical bonds, typically single bonds unless specified otherwise.
• The structural formula provides a visual way to see how the atoms connect with each other in the compound.
• When drawing structural formulas for isomers, it's crucial to show all the unique configurations without duplicating arrangements already depicted.

Understanding structural formulas is essential because it helps differentiate between different isomers. Variations in structural formulas can lead to very different properties, even if they share the same chemical formula.

Heptane

Heptane is an organic compound that belongs to the alkane family, which are saturated hydrocarbons with single bonds only. Its chemical formula is $C_7{H}_{16}$. As the name suggests, it comprises seven carbon atoms ( $\text{hepta}-$ means seven) and sixteen hydrogen atoms.

• Heptane's most straightforward structure is a straight chain where each carbon atom is connected in a row, forming the so-called linear structure of heptane.
• This version is specifically known as "n-heptane," with "n-" indicating a normal straight chain without branches.
• It is an important reference compound in octane rating scales for fuel.
  

Yet, heptane is more than just one compound. It can exist as various isomers, each with a unique arrangement, but retaining the formula $C_7{H}_{16}$. Understanding heptane in its different forms involves recognizing these structural nuances.

Hydrocarbon isomers

Isomers are compounds that have the same molecular formula but differ in the arrangement of atoms within the molecule. For hydrocarbons like ${\text{C}}_7{\text{H}}_{16}$, isomers can be particularly diverse, each exhibiting unique properties. Heptane, for example, has several isomers beyond its linear form.

• Branching of the carbon chain is a key factor in creating isomers. By moving methyl groups ( ${\text{-CH}}_3$) or ethyl groups ( ${\text{-C}}_2{\text{H}}_5$) to different carbon atoms in the main chain, different structures emerge.
• Each unique structure represents a distinct isomer of the hydrocarbon.
• All structural isomers of a given hydrocarbon must satisfy specific rules: each carbon forms four bonds, and no two structures are identical.
  

By exploring these variations, students can better grasp how molecular shapes influence chemical behavior and properties. The study of isomers is fundamental for appreciating the complexity and versatility of organic chemistry.