Chapter 17: Problem 85
(Note: \(\mathrm{H}=+1\) even though it comes second in the formula: \(\mathrm{N}\) is a nommetal.) (a) \(\mathrm{N}=-3\), (b) \(\mathrm{Cr}=+6\),
Short Answer
Expert verified
N has an oxidation state of -3; Cr has an oxidation state of +6.
Step by step solution
01
Understand the Charge of Nitrogen (N)
In compounds, nitrogen (N) can have different oxidation states depending on its bonding. The given exercise indicates that nitrogen has an oxidation number of -3. Nitrogen typically has this oxidation state when it is part of a binary compound with a metal or in the ammonia molecule (NH3).
02
Understand the Charge of Chromium (Cr)
Chromium (Cr) can exhibit various oxidation states in its compounds. The exercise specifies that chromium has an oxidation state of +6. This is a common oxidation state for chromium when it is part of compounds like chromium trioxide (CrO3) or dichromate (Cr2O7^2-).
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chemical Bonding
Chemical bonding is a fundamental concept in chemistry that explains how atoms combine to form molecules. It's the force that holds atoms together within compounds and can come in various types, like ionic, covalent, metallic, and hydrogen bonds. In ionic bonding, atoms donate or accept electrons to achieve a full outer shell, resulting in a positive or negative ion. For example, when a metal reacts with a nonmetal, the metal typically loses electrons to become a positive ion while the nonmetal gains those electrons, becoming a negative ion.
The exercise mentions nitrogen (N) with an oxidation state of -3. This state is typical for nitrogen when it forms a triple bond with another nitrogen atom, as in N2, or when it bonds with metals, suggesting an ionic bond where nitrogen has gained electrons. Understanding how atoms bond is critical for predicting compound properties, reactivity, and structure.
The exercise mentions nitrogen (N) with an oxidation state of -3. This state is typical for nitrogen when it forms a triple bond with another nitrogen atom, as in N2, or when it bonds with metals, suggesting an ionic bond where nitrogen has gained electrons. Understanding how atoms bond is critical for predicting compound properties, reactivity, and structure.
Redox Reactions
Redox reactions, short for reduction-oxidation reactions, are processes where electrons are transferred between two substances. The substance that loses electrons is said to be oxidized, while the one that gains electrons is reduced. Oxidation states, as indicated in the exercise for nitrogen (N) and chromium (Cr), help track these electron transfers.
If we consider chromium (Cr) with an oxidation state of +6, this indicates a highly oxidized state where chromium can act as a strong oxidizing agent, meaning it can accept electrons during a redox reaction. In inorganic chemistry, understanding redox reactions is crucial, as they are fundamental to processes such as energy production, metal corrosion, and biochemical cycles.
If we consider chromium (Cr) with an oxidation state of +6, this indicates a highly oxidized state where chromium can act as a strong oxidizing agent, meaning it can accept electrons during a redox reaction. In inorganic chemistry, understanding redox reactions is crucial, as they are fundamental to processes such as energy production, metal corrosion, and biochemical cycles.
Periodic Table Elements
The periodic table systematically categorizes elements, providing a wealth of information about their properties based on their position. Elements are arranged by increasing atomic number, and their physical and chemical properties exhibit periodic trends, such as electronegativity and ionization energies.
Within the periodic table, elements like nitrogen and chromium each have their unique behaviors and tendencies. Nitrogen, a nonmetal found in Group 15, tends to form compounds in which it has a -3 oxidation state due to its high electronegativity and need to gain three electrons to complete its valence shell. Conversely, chromium, a transition metal, shows variable oxidation states because it can lose different numbers of electrons available in its d orbitals, resulting in common oxidation states like +2, +3, and +6. Knowledge of periodic trends helps us predict how elements will interact and bond with each other.
Within the periodic table, elements like nitrogen and chromium each have their unique behaviors and tendencies. Nitrogen, a nonmetal found in Group 15, tends to form compounds in which it has a -3 oxidation state due to its high electronegativity and need to gain three electrons to complete its valence shell. Conversely, chromium, a transition metal, shows variable oxidation states because it can lose different numbers of electrons available in its d orbitals, resulting in common oxidation states like +2, +3, and +6. Knowledge of periodic trends helps us predict how elements will interact and bond with each other.
Inorganic Chemistry
Inorganic chemistry focuses on the behavior and synthesis of inorganic and organometallic compounds. This branch of chemistry covers all chemical compounds except the myriad organic compounds (carbon based), which are the subjects of organic chemistry. It includes the study of minerals, metals, and other non-carbon-based compounds.
In the context of our exercise, nitrogen and chromium are elements that fall under inorganic chemistry. When discussing oxidation states within inorganic chemistry, it is crucial to analyze and predict how different elements like chromium with a +6 oxidation state can exist in compounds, influencing their geometry, reactivity, and magnetic properties. Recognizing these oxidation states is important when balancing redox reactions, a common exercise in inorganic chemistry courses.
In the context of our exercise, nitrogen and chromium are elements that fall under inorganic chemistry. When discussing oxidation states within inorganic chemistry, it is crucial to analyze and predict how different elements like chromium with a +6 oxidation state can exist in compounds, influencing their geometry, reactivity, and magnetic properties. Recognizing these oxidation states is important when balancing redox reactions, a common exercise in inorganic chemistry courses.