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Soil vapor extraction (SVE) is used to remove volatile organic pollutants, such as chlorinated solvents, from soil at hazardous waste sites. Vent wells are drilled, and a vacuum pump is applied to the subsurface. (a) How does this method remove pollutants? (b) Why does heating combined with SVE speed the process?

Short Answer

Expert verified
SVE uses a vacuum to vaporize and remove pollutants. Heating enhances volatilization, speeding up the process.

Step by step solution

01

Understanding Soil Vapor Extraction (SVE)

SVE involves drilling vent wells into contaminated soil and applying a vacuum to remove volatile organic compounds (VOCs). The vacuum induces air flow through the soil, vaporizing the pollutants, which are then captured and treated.
02

Mechanism of Pollutant Removal

The method removes pollutants by taking advantage of their volatility. As the vacuum pump draws air through the soil, it evaporates the contaminants. These vapors are then extracted from the soil and collected at the surface for treatment.
03

Introduction to Heating

Heating the soil increases the temperature, which enhances the volatility of the contaminants. When combined with SVE, this speeds up the evaporation process, making it faster to remove the pollutants.
04

Impact of Increased Temperature

Higher temperatures reduce the adherence of pollutants to soil particles and increase their vapor pressure. This causes contaminants to evaporate more quickly, thereby improving the efficiency of the SVE process.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Volatile Organic Compounds (VOCs)
Volatile Organic Compounds (VOCs) are chemicals that easily become vapors or gases. They are called 'volatile' because they evaporate quickly at room temperature. VOCs can be found in many industrial and household products like paint, fuels, and cleaning agents. Some common examples include benzene, toluene, and chlorinated solvents.

When VOCs are present in soil and groundwater, they pose a risk to human health and the environment. Inhalation of VOCs can cause adverse health effects such as headaches, dizziness, and even damage to the liver and kidneys. This makes it crucial to remediate areas contaminated with VOCs.

Soil Vapor Extraction (SVE) is one essential method used to remove VOCs from contaminated soil. By applying a vacuum to the subsurface, it enables the volatilization of these pollutants. The vapors are extracted and treated, making the environment safer.
Environmental Remediation
Environmental remediation refers to the processes used to remove pollution or contaminants from environmental media such as soil, groundwater, sediment, or surface water. The goal is to protect human health and restore the environment.

Remediation methods can vary depending on the type and extent of contamination. Soil Vapor Extraction (SVE) is particularly effective for volatile organic compounds (VOCs). The process involves:
  • Drilling vent wells into the contaminated soil
  • Applying a vacuum through these wells
  • Inducing airflow to volatilize and capture the pollutants

Effective environmental remediation is crucial for reclaiming polluted sites and preventing the spread of contaminants. This is especially important for lands being converted for residential or recreational use, ensuring long-term safety and sustainability.
Thermal Enhancement in Soil Treatment
Thermal enhancement is an advanced technique used to improve the efficiency of soil treatment methods like Soil Vapor Extraction (SVE). Heating the soil increases the temperature, which boosts the volatility of contaminants. Here’s how it works:
  • Heat is applied to the contaminated soil
  • Higher temperatures increase the vapor pressure of the pollutants
  • This reduces the contaminants' adherence to soil particles

By facilitating faster evaporation of pollutants, thermal enhancement speeds up the entire SVE process. This combination can be particularly effective for removing stubborn VOCs that are tightly bound to soil particles.

Moreover, thermal enhancement can be realized through various methods, including electrical resistance heating, steam injection, or radiofrequency heating. The advantages of this approach include quicker remediation times and increased pollutant removal efficiency, making it a powerful tool in environmental cleanup initiatives.

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Most popular questions from this chapter

Both solid \(\mathrm{Kr}\) and solid Cu consist of individual atoms. Why do their physical properties differ so much?

A 4.7-L sealed bottle containing 0.33 g of liquid ethanol, \(\mathrm{C}_{2} \mathrm{H}_{6} \mathrm{O},\) is placed in a refrigerator and reaches equilibrium with its vapor at \(-11^{\circ} \mathrm{C}\). (a) What mass of ethanol is present in the vapor? (b) When the container is removed and warmed to room temperature, \(20 .{ }^{\circ} \mathrm{C},\) will all the ethanol vaporize? (c) How much liquid ethanol would be present at \(0.0^{\circ} \mathrm{C}\) ? The vapor pressure of ethanol is \(10 .\) torr at \(-2.3^{\circ} \mathrm{C}\) and \(40 .\) torr at \(19^{\circ} \mathrm{C}\).

Mercury (Hg) vapor is toxic and readily absorbed from the lungs. At \(20 .^{\circ} \mathrm{C},\) mercury \(\left(\Delta H_{\mathrm{vap}}=59.1 \mathrm{~kJ} / \mathrm{mol}\right)\) has a vapor pressure of \(1.20 \times 10^{-3}\) torr, which is high enough to be hazardous. To reduce the danger to workers in processing plants, \(\mathrm{Hg}\) is cooled to lower its vapor pressure. At what temperature would the vapor pressure of \(\mathrm{Hg}\) be at the safer level of \(5.0 \times 10^{-5}\) torr?

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Many heat-sensitive and oxygen-sensitive solids, such as camphor, are purified by warming under vacuum. The solid vaporizes directly, and the vapor crystallizes on a cool surface. What phase changes are involved in this method?

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