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Problem 53

Draw the resonance structures of the benzene molecule. Why is benzene more stable than one would expect if the ring contained three carbon-carbon double bonds?

Problem 54

Polystyrene plastic is a hydrocarbon that consists of a long chain of carbon atoms joined by single bonds in which every other carbon is attached to a benzene ring. The ring is attached by replacing a hydrogen atom of benzene with a single bond to the carbon chain. Sketch a portion of a polystyrene molecule that contains five benzene rings.

Problem 55

Sketch the structures for (a) methane, (b) ethane, and (c) propane.

Problem 56

Draw the structure for a hydrocarbon that has a chain of six carbon atoms linked by single bonds. How many hydrogen atoms does the molecule have? What is the molecular formula for the compound?

Problem 63

In each of the following pairs of compounds, which would have the larger lattice energy: (a) \(\mathrm{CaO}\) or \(\mathrm{Al}_{2} \mathrm{O}_{3},\) (b) \(\mathrm{BeO}\) or \(\mathrm{SrO},\) (c) \(\mathrm{NaCl}\) or \(\mathrm{NaBr}\) ?

Problem 64

In each of the following pairs of compounds, which would have the larger lattice energy: (a) \(\mathrm{MgO}\) or \(\mathrm{CaO}\) (b) \(\mathrm{Na}_{2} \mathrm{O}\) or \(\mathrm{MgO}\) (c) \(\mathrm{Ca}_{3} \mathrm{P}_{2}\) or \(\mathrm{CaO}\) ?

Problem 67

Explain what happens to the electron configurations of \(\mathrm{Mg}\) and \(\mathrm{Br}\) when they react to form magnesium bromide

Problem 68

Describe what happens to the electron configurations of lithium and nitrogen when they react to form the lithium nitride.

Problem 70

What are the electron configurations of the \(\mathrm{Bi}^{3+}\) and \(\mathrm{Bi}^{5+}\) ions?

Problem 71

Write the abbreviated electron configuration of the \(\mathrm{Mn}^{3+}\) ion. How many unpaired electrons does the ion contain?

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