Dinitrogen trioxide, \(\mathrm{N}_{2} \mathrm{O}_{3},\) is largely dissociated
into \(\mathrm{NO}\) and \(\mathrm{NO}_{2}\) in the gas phase where there exists
the equilibrium, \(\mathrm{N}_{2} \mathrm{O}_{3} \rightleftharpoons
\mathrm{NO}+\mathrm{NO}_{2}\). In an effort to
determine the structure of \(\mathrm{N}_{2} \mathrm{O}_{3}\), a mixture of
\(\mathrm{NO}\) and \({ }^{*} \mathrm{NO}_{2}\) was prepared containing
isotopically labeled \(\mathrm{N}\) in the \(\mathrm{NO}_{2}\). After a period of
time the mixture was analyzed and found to contain substantial amounts of both
\({ }^{*} \mathrm{NO}\) and \({ }^{*} \mathrm{NO}_{2}\). Explain how this is
consistent with the structure for \(\mathrm{N}_{2} \mathrm{O}_{3}\) being ONONO.