Chapter 13: Problem 47
How does a catalyst increase the rate of a chemical reaction?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 13: Problem 47
How does a catalyst increase the rate of a chemical reaction?
These are the key concepts you need to understand to accurately answer the question.
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Get started for freeIf the reaction $$\mathrm{NO}_{2}+\mathrm{CO} \longrightarrow \mathrm{NO}+\mathrm{CO}_{2}$$ occured by a one-step collision process, what would be the expected rate law for the reaction? The actual rate law is rate \(=k\left[\mathrm{NO}_{2}\right]^{2}\). Could the reaction actually occur by a one-step collision between \(\mathrm{NO}_{2}\) and CO? Explain.
Hydrogen iodide decomposes according to the equation, $$2 \mathrm{HI}(g) \longrightarrow \mathrm{H}_{2}(g)+\mathrm{I}_{2}(g)$$The reaction is second order and has a rate constant equal to \(1.6 \times 10^{-3} \mathrm{~L} \mathrm{~mol}^{-1} \mathrm{~s}^{-1}\) at \(750^{\circ} \mathrm{C}\). If the initial concentration of HI in a container is \(3.4 \times 10^{-2} M\), how many minutes will it take for the concentration to be reduced $$\text { to } 8.0 \times 10^{-4} \mathrm{M}$$.
A reaction has the following mechanism: $$\begin{aligned}2 \mathrm{NO} \longrightarrow & \mathrm{N}_{2} \mathrm{O}_{2} \\\\\mathrm{~N}_{2} \mathrm{O}_{2}+\mathrm{H}_{2} & \longrightarrow \mathrm{N}_{2} \mathrm{O}+\mathrm{H}_{2} \mathrm{O} \\ \mathrm{N}_{2} \mathrm{O}+\mathrm{H}_{2} \longrightarrow & \mathrm{N}_{2}+\mathrm{H}_{2} \mathrm{O}\end{aligned}$$ What is the net overall change that occurs in this reaction? Identify any intermediates in the reaction.
What is the purpose of the catalytic converter that most automobiles use today? Is the catalyst heterogeneous or homogeneous?
What is a homogeneous reaction? What is a heterogeneous reaction? Give examples.
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