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(a) What is the electrostatic potential energy (in joules) between an electron and a proton that are separated by \(230 \mathrm{pm}\) ? (b) What is the change in potential energy if the distance separating the electron and proton is increased to \(1.0 \mathrm{nm}\) ? (c) Does the potential energy of the two particles increase or decrease when the distance is increased to \(1.0 \mathrm{nm}\) ?

Short Answer

Expert verified
a) The electrostatic potential energy between the electron and proton separated by 230 pm is: \(U_1 = \dfrac{(8.99 * 10^9 N m^2/C^2)(1.60 * 10^{-19} C)(-1.60 * 10^{-19} C)}{230 * 10^{-12} m} \approx -4.99 * 10^{-18} J\) b) The electrostatic potential energy between the electron and proton separated by 1.0 nm is: \(U_2 = \dfrac{(8.99 * 10^9 N m^2/C^2)(1.60 * 10^{-19} C)(-1.60 * 10^{-19} C)}{1.0 * 10^{-9} m} \approx -2.30 * 10^{-18} J\) c) The change in potential energy is: \(\Delta U = U_2 - U_1 \approx -2.30 * 10^{-18} J - (-4.99 * 10^{-18} J) \approx 2.69 * 10^{-18} J\) Since \(\Delta U > 0\), the potential energy of the two particles increases when the distance is increased to 1.0 nm.

Step by step solution

01

Convert Distances to Meters

First, we need to convert the given distances to meters to be compatible with the units of the electrostatic constant: - 230 pm = 230 * 10^(-12) meters - 1.0 nm = 1.0 * 10^(-9) meters
02

Constants and Initial Values

For solving this problem, we require the following constants and initial values: - \(k_e = 8.99 * 10^9 \ N m^2/C^2\) (electrostatic constant) - Charge of a proton, \(q_p = 1.60 * 10^{-19} C\) - Charge of an electron, \(q_e = -1.60 * 10^{-19} C\)
03

Calculate Potential Energy at 230 pm

Using the electrostatic potential energy formula for a distance of 230 pm (230 * 10^(-12) meters): \(U_1 = \dfrac{(8.99 * 10^9 N m^2/C^2)(1.60 * 10^{-19} C)(-1.60 * 10^{-19} C)}{230 * 10^{-12} m}\) Calculate \(U_1\) to find the potential energy.
04

Calculate Potential Energy at 1.0 nm

Using the electrostatic potential energy formula for a distance of 1.0 nm (1.0 * 10^(-9) meters): \(U_2 = \dfrac{(8.99 * 10^9 N m^2/C^2)(1.60 * 10^{-19} C)(-1.60 * 10^{-19} C)}{1.0 * 10^{-9} m}\) Calculate \(U_2\) to find the potential energy.
05

Change in Potential Energy

To find the change in potential energy, subtract the initial potential energy from the final potential energy: \(\Delta U = U_2 - U_1\) Calculate \(\Delta U\) to find the change in potential energy.
06

Potential Energy Increase or Decrease

Determine if the potential energy increased or decreased by analyzing the sign of \(\Delta U\). If \(\Delta U > 0\), the potential energy increased; if \(\Delta U < 0\), the potential energy decreased.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Coulomb's Law
Coulomb's Law is a fundamental principle in physics that describes the electrostatic interaction between electrically charged particles.
It states that the force between two charges is proportional to the product of the charges, and inversely proportional to the square of the distance between them. This can be expressed with the formula:
  • F = \( \dfrac{k_e \cdot |q_1 \cdot q_2|}{r^2} \)
Here, \( F \) is the force between the charges, \( k_e \) is the electrostatic constant, \( q_1 \) and \( q_2 \) are the magnitudes of the charges, and \( r \) is the distance between the centers of the two charges.
In the context of the given exercise, Coulomb's Law helps quantify the attraction between an electron and a proton, which are two charged particles. These interactions are influenced by the magnitude of their charges and the distance separating them. Understanding this principle is crucial for computing potential energy in electrostatic contexts. By integrating Coulomb's law with dimensional analysis, we can determine potential energy values for various distances between particles.
Electron-Proton Interaction
The interaction between an electron and a proton is a classic example of electrostatic attraction. Electrons are negatively charged particles, while protons carry a positive charge. As per Coulomb's Law, opposite charges attract each other, and thus electrons and protons are naturally drawn towards one another.
In the exercise, this principle underpins the calculation of the potential energy between the two particles. The charge of a proton is \( q_p = 1.60 \times 10^{-19} C \), while the charge of an electron is \( q_e = -1.60 \times 10^{-19} C \).
This interaction determines how the potential energy is calculated, as one electron and one proton create a dipole with specific potential energy that depends on their separation distance.
  • An electron in proximity to a proton results in a lower potential energy state.
  • An increased separation distance would typically lead to a less negatively charged potential energy.
Such interactions are essential in understanding chemical bonds and reactions, as the energy levels between particles can indicate potential molecular arrangements and reactions.
Potential Energy Change
Potential energy change is critical when examining how distances between charged particles influence their energy states. In the context of the exercise, potential energy is calculated for two different separation distances between an electron and a proton.
This concept is highlighted by examining the change in potential energy when the separation increases from 230 pm to 1.0 nm. Using the formula:
  • \( U = \dfrac{k_e \cdot q_1 \cdot q_2}{r} \)
we find the potential energy at each distance and the difference between them. The change in potential energy, represented as \( \Delta U = U_2 - U_1 \), tells us about the energy dynamics as distance varies.
For this system:
  • If \( \Delta U < 0 \), the system loses energy, often when moving closer.
  • If \( \Delta U > 0 \), the system gains energy when moving apart.
Understanding these changes helps in predicting the behavior of atomic and molecular interactions.
Distance in Chemistry
Distance is a fundamental factor in chemistry, affecting the interactions and energy level of atoms and molecules. By analyzing how particles interact over different distances, we can infer a lot about the molecular structure and stability.
In the exercise example, the separation between an electron and a proton is considered at two points: 230 pm and 1.0 nm. Distance affects the potential energy calculated, where a smaller distance typically results in stronger interactions and lower potential energy due to increased attraction.
This concept is especially relevant to chemical bonds, where:
  • Shorter distances often lead to stronger bonds.
  • Increasing distance can weaken interaction energy, signifying the potential dissociation of bonds.
Understanding these principles is crucial in fields such as organic chemistry and molecular physics, where bonding patterns and chemical reactions rely on the electrostatic interactions dictated by the distances between atoms and molecules.

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Most popular questions from this chapter

Consider the following reaction: $$ 2 \mathrm{CH}_{3} \mathrm{OH}(g) \longrightarrow 2 \mathrm{CH}_{4}(g)+\mathrm{O}_{2}(g) \quad \Delta H=+252.8 \mathrm{~kJ} $$ (a) Is this reaction exothermic or endothermic? (b) Calculate the amount of heat transferred when \(24.0 \mathrm{~g}\) of \(\mathrm{CH}_{3} \mathrm{OH}(g)\) is decomposed by this reaction at constant pressure. (c) For a given sample of \(\mathrm{CH}_{3} \mathrm{OH},\) the enthalpy change during the reaction is \(82.1 \mathrm{~kJ}\). How many grams of methane gas are produced? (d) How many kilojoules of heat are released when \(38.5 \mathrm{~g}\) of \(\mathrm{CH}_{4}(g)\) reacts completely with \(\mathrm{O}_{2}(g)\) to form \(\mathrm{CH}_{3} \mathrm{OH}(g)\) at constant pressure?

(a) Why is the change in internal energy \(\Delta E\) usually harder to measure than the change in enthalpy \(\Delta H ?(\mathbf{b}) E\) is a state function, but \(q\) is not a state function. Explain. (c) For a given process at constant pressure, \(\Delta H\) is negative. Is the process endothermic or exothermic?

Assume that 2 moles of water are formed according to the following reaction at constant pressure \((101.3 \mathrm{kPa})\) and constant temnerature \((298 \mathrm{~K});\) $$ 2 \mathrm{H}_{2}(g)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(l) $$ (a) Calculate the pressure-volume work for this reaction. (b) Calculate \(\Delta E\) for the reaction using your answer to (a).

The standard enthalpies of formation of gaseous propyne \(\left(\mathrm{C}_{3} \mathrm{H}_{4}\right),\) propylene \(\left(\mathrm{C}_{3} \mathrm{H}_{6}\right),\) and propane \(\left(\mathrm{C}_{3} \mathrm{H}_{8}\right)\) are \(+185.4,+20.4,\) and \(-103.8 \mathrm{~kJ} / \mathrm{mol}\), respectively. (a) Calculate the heat evolved per mole on combustion of each substance to yield \(\mathrm{CO}_{2}(g)\) and \(\mathrm{H}_{2} \mathrm{O}(g) .\) (b) Calculate the heat evolved on combustion of \(1 \mathrm{~kg}\) of each substance. \((\mathbf{c})\) Which is the most efficient fuel in terms of heat evolved per unit mass?

Without doing any calculations, predict the sign of \(\Delta H\) for each of the following reactions: (a) \(2 \mathrm{NO}_{2}(g) \longrightarrow \mathrm{N}_{2} \mathrm{O}_{4}(g)\) (b) \(2 \mathrm{~F}(g) \longrightarrow \mathrm{F}_{2}(g)\) (c) \(\mathrm{Mg}^{2+}(g)+2 \mathrm{Cl}^{-}(g) \longrightarrow \mathrm{MgCl}_{2}(s)\) (d) \(\mathrm{HBr}(g) \longrightarrow \mathrm{H}(g)+\mathrm{Br}(g)\)

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