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As a metal such as lead melts, what happens to (a) the average kinetic energy of the atoms and (b) the average distance between the atoms?

Short Answer

Expert verified
As a metal like lead melts, (a) the average kinetic energy of the atoms increases due to the temperature rise and faster atomic movement, and (b) the average distance between the atoms increases as the material transitions from a closely packed solid-state lattice to a less ordered liquid state with increased repulsion forces.

Step by step solution

01

Understand the concept of kinetic energy

Kinetic energy is the energy of motion. In the context of atoms, it directly relates to the speed at which the atoms are moving within the material.
02

Consider the effect of temperature

When a metal melts, the temperature increases, meaning the atoms have more energy. As the atoms gain more energy, they move faster. This results in an increase in the average kinetic energy of the atoms.
03

Final answer for (a)

As a metal such as lead melts, the average kinetic energy of the atoms increases. #b) The average distance between the atoms#
04

Understand the concept of atomic spacing

The average distance between the atoms refers to the space between individual atoms within the material.
05

Consider the transition from solid to liquid state

As a metal melts, it transitions from a solid state to a liquid state. In the solid state, the atoms are arranged in a fixed, closely packed lattice. In the liquid state, the atoms lose their fixed positions and flow freely, which means the arrangement becomes less ordered.
06

Account for the increase in energy

In the liquid state, the atoms have more energy and move more rapidly, causing the atoms to collide and repel each other. This leads to an increase in the average distance between the atoms due to the increased repulsion forces.
07

Final answer for (b)

As a metal such as lead melts, the average distance between the atoms increases.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Kinetic Energy in Melting Metals
Kinetic energy is a fundamental concept in physics, representing the energy that an object possesses due to its motion. When we think about metals like lead undergoing a phase transition from solid to liquid, we need to consider the behavior of the atoms. As the temperature of the metal increases during melting, the atoms gain energy, causing them to vibrate and move more vigorously.
This increase in motion translates directly to an increase in kinetic energy. As a result, as metal melts, the average kinetic energy of the atoms within the metal increases, signifying faster-moving particles.
Phase Transition from Solid to Liquid
The phase transition from solid to liquid is a fascinating phenomenon, particularly in metals such as lead. In a solid state, metal atoms are arranged in a structured, closely packed lattice. However, during melting, the atoms absorb energy and overcome the rigid lattice structure, transitioning into a liquid form.
Atoms in a liquid state flow more freely and are less ordered compared to their solid counterparts. This change is significant in understanding the nature of metals at different temperatures. One can visualize this transition as moving from a regimented marching band (solid) to a lively dance floor (liquid), highlighting less order and more movement.
Atomic Spacing During Melting
One important aspect of the melting process is the change in atomic spacing. The term 'atomic spacing' refers to the distance between atoms in a material. In the solid state, atoms are tightly packed in a fixed structure; however, when a metal like lead melts, the atoms shift into a more random distribution.
As the temperature rises, the increased energy causes atoms to move more rapidly and frequently collide, inducing repulsion forces that increase the distance between them. This increase in atomic spacing is crucial as it indicates a shift towards the liquid state, allowing atoms greater freedom to move and occupy a larger volume.

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Most popular questions from this chapter

Benzoic acid, \(\mathrm{C}_{6} \mathrm{H}_{5} \mathrm{COOH},\) melts at \(122^{\circ} \mathrm{C}\). The density in the liquid state at \(130^{\circ} \mathrm{C}\) is \(1.08 \mathrm{~g} / \mathrm{cm}^{3} .\) The density of solid benzoic acid at \(15^{\circ} \mathrm{C}\) is \(1.266 \mathrm{~g} / \mathrm{cm}^{3}\). (a) In which of these two states is the average distance between molecules greater? (b) If you converted a cubic centimeter of liquid benzoic acid into a solid, would the solid take up more, or less, volume than the original cubic centimeter of liquid?

Propyl alcohol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\right)\) and isopropyl alcohol \(\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}\right],\) whose space- filling models are shown, have boiling points of 97.2 and \(82.5^{\circ} \mathrm{C}\), respectively. Explain why the boiling point of propyl alcohol is higher, even though both have the molecular formula, \(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}\).

You are high up in the mountains and boil water to make some tea. However, when you drink your tea, it is not as hot as it should be. You try again and again, but the water is just not hot enough to make a hot cup of tea. Which is the best explanation for this result? (a) High in the mountains, it is probably very dry, and so the water is rapidly evaporating from your cup and cooling it. (b) High in the mountains, it is probably very windy, and so the water is rapidly evaporating from your cup and cooling it. (c) High in the mountains, the air pressure is significantly less than \(101.3 \mathrm{kPa}\), so the boiling point of water is much lower than at sea level. (d) High in the mountains, the air pressure is significantly less than \(101.3 \mathrm{kPa}\), so the boiling point of water is much higher than at sea level.

The vapor pressure of acetone \(\left(\mathrm{CH}_{3} \mathrm{COCH}_{3}\right)\) at \(19^{\circ} \mathrm{C}\) is 5.33 kPa. A 3.50-g sample of acetone is placed in a \(2.00 \mathrm{~L}\) container at \(22^{\circ} \mathrm{C}\). If the container is closed and the acetone is allowed to reach equilibrium with its vapor, how many grams of liquid acetone remain? (Assume that the vapor behaves like an ideal gas.)

True or false: (a) Molecules containing polar bonds must be polar molecules and have dipole-dipole forces. (b) For the halogen gases, the dispersion forces decrease while the boiling points increase as you go down the column in the periodic table. (c) In terms of the total attractive forces for a given substance, the more polar bonds there are in a molecule, the stronger the dipole-dipole interaction. \(\mathbf{d}\) ) All other factors being the same, total attractive forces between linear molecules are greater than those between molecules whose shapes are nearly spherical. (e) The more electronegative the atom, the more polarizable it is.

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