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List the three states of matter in order of (a) increasing molecular disorder and \((\mathbf{b})\) increasing intermolecular attraction. (c) Which state of matter is most easily compressed?

Short Answer

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(a) Solid, Liquid, Gas. (b) Gas, Liquid, Solid. (c) Gas is most easily compressed.

Step by step solution

01

Understanding Molecular Disorder

Matter exists in three common states: solid, liquid, and gas. Molecular disorder increases from solid, where particles are tightly packed and orderly, to liquid, where they are less orderly but still connected, to gas, where particles are free and highly disordered.
02

Order of Increasing Molecular Disorder

To list the states of matter in order of increasing molecular disorder: 1) Solid, 2) Liquid, 3) Gas. This is because particles in solids have the least freedom to move compared to those in liquids and gases.
03

Understanding Intermolecular Attraction

Intermolecular attraction is strongest in solids where particles attract each other strongly, weaker in liquids, and weakest in gases where particles are far apart.
04

Order of Increasing Intermolecular Attraction

To list the states of matter in order of increasing intermolecular attraction: 1) Gas, 2) Liquid, 3) Solid. Intermolecular attraction increases as you move from a gas to a solid.
05

Comprehensibility and Compression

Gases are the most easily compressed state of matter due to the large spaces between particles, which can be pushed closer together under pressure.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Molecular Disorder
Understanding molecular disorder involves observing how the particles within different states of matter are organized. In solids, particles are neatly packed into a regular pattern, making them highly ordered.
In liquids, although the particles are still in close proximity, they lack the rigid structure found in solids, allowing them to flow more freely. This results in a moderate degree of molecular disorder.
Lastly, gases exhibit the highest level of molecular disorder, as their particles are spaced far apart and move independently, with no fixed positions.
  • Solids: High order, particles are fixed.
  • Liquids: Moderate order, particles can move around each other.
  • Gases: High disorder, particles move freely.
Understanding this concept helps explain why substances behave differently in their various states.
Intermolecular Attraction
Intermolecular attraction refers to the forces holding particles of a substance together. In solids, these forces are strongest, helping maintain a fixed volume and shape due to the particles being closely bonded.
Liquids possess weaker intermolecular forces than solids, allowing the particles to slide past one another, which enables the liquid to take the shape of its container while maintaining a constant volume.
For gases, intermolecular attraction is the weakest. The particles are far apart and move independently, allowing gases to expand to fill any available volume.
  • Solids: Strong attraction, keeps particles fixed.
  • Liquids: Moderate attraction, allows flow.
  • Gases: Weak attraction, particles move independently.
Intermolecular forces are key in defining the physical properties of a substance in different environments.
Compression of Matter
The ability to compress a substance depends on the spaces between its particles. Solids are the least compressible because their particles are tightly packed and resist further compression.
Liquids are slightly more compressible than solids but still offer significant resistance because the particles, although not as tight as in solids, are still close.
In contrast, gases can be easily compressed. The large empty spaces between the particles in a gaseous state mean they can be packed closer together when pressure is applied, allowing for significant volume reduction.
  • Solids: Least compressible, tightly packed particles.
  • Liquids: Limited compression, particles close together.
  • Gases: Most compressible, large spaces between particles.
Understanding compression is crucial for applications requiring volume and density changes, like in gas storage and transportation.

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Most popular questions from this chapter

The molecules Propanol \(\quad\) Ethyl methyl ether have the same molecular formula \(\left(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}\right)\) but different chemical structures, (a) Which molecule(s), if any, can engage in hydrogen bonding? (b) Which molecule do you expect to have a larger dipole moment? \((\mathbf{c})\) One of these \(\mathrm{mol}\) ecules has a normal boiling point of \(97,2^{\circ} \mathrm{C},\) while the other one has a normal boiling point of \(10.8^{\circ} \mathrm{C}\). Assign each molecule to its normal boiling point. [Sections 11.2 and 11.5\(]\)

The table below lists the density of substance \(\mathrm{X}\) at various temperatures and at \(101.3 \mathrm{kPa}\). The normal melting point of substance \(X\) is \(80 \mathrm{~K}\). \begin{tabular}{cc} \hline Temperature \((\mathrm{K})\) & Density \((\mathrm{mol} / \mathrm{L})\) \\ \hline 90 & 35.2 \\ 100 & 33.8 \\ 110 & 32.1 \\ 120 & 0.136 \\ 140 & 0.110 \\ 160 & 0.0893 \\ 180 & 0.0796 \\ \hline \end{tabular} (a) Over what temperature range is substance \(X\) a solid? (b) Over what temperature range is \(\mathrm{X}\) a liquid? \((\mathbf{c})\) Over what temperature range in the table is \(\mathrm{X}\) a gas? (d) Estimate the normal boiling point of \(X .\) (e) Given that \(X\) is a nonpolar molecule, suggest the kind of intermolecular forces in \(\mathrm{X}\).

Propyl alcohol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\right)\) and isopropyl alcohol \(\left[\left(\mathrm{CH}_{3}\right)_{2} \mathrm{CHOH}\right],\) whose space- filling models are shown, have boiling points of 97.2 and \(82.5^{\circ} \mathrm{C}\), respectively. Explain why the boiling point of propyl alcohol is higher, even though both have the molecular formula, \(\mathrm{C}_{3} \mathrm{H}_{8} \mathrm{O}\).

Freon, \(\mathrm{CCl}_{2} \mathrm{~F}_{2},\) and dichloromethane, \(\mathrm{CH}_{2} \mathrm{Cl}_{2},\) are common organic substances. Freon is a gas with a normal boiling point of \(-29.8{ }^{\circ} \mathrm{C}\); dichloromethane's normal boiling point is \(39.6^{\circ} \mathrm{C}\). Which statement is the best explanation of these data? (a) Dichloromethane can form hydrogen bonds, but freon cannot. (b) Dichloromethane has a larger dipole moment than freon. (c) Freon is more polarizable than dichloromethane.

For many years drinking water has been cooled in hot climates by evaporating it from the surfaces of canvas bags of porous clay pots. How many grams of water can be cooled from 35 to \(20^{\circ} \mathrm{C}\) by the evaporation of \(60 \mathrm{~g}\) of water? (The heat of vaporization of water in this temperature range is \(2.4 \mathrm{~kJ} / \mathrm{g}\). The specific heat of water is \(4.18 \mathrm{~J} / \mathrm{g}-\mathrm{K}\).)

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