Chapter 5: Problem 33
You are given \(\Delta H\) for a process that occurs at constant pressure. What additional information do you need to determine \(\Delta E\) for the process?
Chapter 5: Problem 33
You are given \(\Delta H\) for a process that occurs at constant pressure. What additional information do you need to determine \(\Delta E\) for the process?
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Get started for freeBurning methane in oxygen can produce three different carbon-containing products: soot (very fine particles of graphite), \(\mathrm{CO}(\mathrm{g})\), and \(\mathrm{CO}_{2}(\mathrm{~g})\). (a) Write three balanced equations for the reaction of methane gas with oxygen to produce these three products. In each case assume that \(\mathrm{H}_{2} \mathrm{O}(l)\) is the only other product. (b) Determine the standard enthalpies for the reactions in part (a). (c) Why, when the oxygen supply is adequate, is \(\mathrm{CO}_{2}(g)\) the predominant carbon- containing product of the combustion of methane?
(a) Why are tables of standard enthalpies of formation so useful? (b) What is the value of the standard enthalpy of formation of an element in its most stable form? (c) Write the chemical equation for the reaction whose enthalpy change is the standard enthalpy of formation of glucose, \(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}(s), \Delta H_{f}^{\circ}\left[\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right]\).
Consider the following reaction: $$ 2 \mathrm{Mg}(s)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{MgO}(s) \quad \Delta H=-1204 \mathrm{~kJ} $$ (a) Is this reaction exothermic or endothermic? (b) Calculate the amount of heat transferred when \(2.4 \mathrm{~g}\) of \(\mathrm{Mg}(\mathrm{s})\) reacts at constant pressure. (c) How many grams of \(\mathrm{MgO}\) are produced during an enthalpy change of \(-96.0 \mathrm{~kJ} ?\) (d) How many kilojoules of heat are absorbed when \(7.50 \mathrm{~g}\) of \(\mathrm{MgO}(s)\) is decomposed into \(\mathrm{Mg}(\mathrm{s})\) and \(\mathrm{O}_{2}(g)\) at constant pressure?
A watt is a measure of power (the rate of energy change) equal to \(1 \mathrm{~J} / \mathrm{s}\). (a) Calculate the number of joules in a kilowatt- hour. (b) An adult person radiates heat to the surroundings at about the same rate as a 100 -watt electric incandescent lightbulb. What is the total amount of energy in kcal radiated to the surroundings by an adult in 24 hours?
Consider the following hypothetical reactions: $$ \begin{array}{ll} \mathrm{A} \rightarrow \mathrm{B} & \Delta H=+30 \mathrm{~kJ} \\ \mathrm{~B} \longrightarrow \mathrm{C} & \Delta H=+60 \mathrm{~kJ} \end{array} $$ (a) Use Hess's law to calculate the enthalpy change for the reaction \(\mathrm{A}-\cdots \mathrm{C}\) (b) Construct an enthalpy diagram for substances \(\mathrm{A}, \mathrm{B}\), and \(\mathrm{C}\), and show how Hess's law applies.
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