Chapter 25: Problem 16
Give the general formula for any cyclic alkene, that is, a cyclic hydrocarbon with one double bond.
Chapter 25: Problem 16
Give the general formula for any cyclic alkene, that is, a cyclic hydrocarbon with one double bond.
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Get started for freeImagine a single DNA strand containing a section with the following base sequence: \(5^{\prime}\) -GCATTGGC-3'. What is the base sequence of the complementary strand? (The two strands of DNA will come together in an antiparallel fashion: that is, \(5^{\prime}-\mathrm{TAG}-3^{\prime}\) will bind to \(3^{\prime}-\mathrm{ATC}-5^{\prime} .\) )
Although there are silicon analogs of alkanes, silicon analogs of alkenes or alkynes are virtually unknown. Suggest an explanation.
There are no known stable cyclic compounds with ring sizes of seven or less that have an alkyne linkage in the ring. Why is this? Could a ring with a larger number of carbon atoms accommodate an alkyne linkage? Explain.
Indole smells rather terrible in high concentrations but has a pleasant floral-like odor when highly diluted. It has the following structure: Indole is a planar molecule. The nitrogen is a very weak base, with a \(K_{b}\) of \(2 \times 10^{-12}\). Explain how this information indicates that the indole molecule is aromatic in character.
Explain why the boiling point of ethanol \(\left(78^{\circ} \mathrm{C}\right)\) is much higher than that of its isomer, dimethyl ether \(\left(-25^{\circ} \mathrm{C}\right)\) and why the boiling point of \(\mathrm{CH}_{2} \mathrm{~F}_{2}\left(-52{ }^{\circ} \mathrm{C}\right)\) is far above that of \(\mathrm{CH}_{4}\left(-128^{\circ} \mathrm{C}\right)\).
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