Chapter 18: Problem 37
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
Chapter 18: Problem 37
List the common products formed when an organic material containing the elements carbon, hydrogen, oxygen, sulfur, and nitrogen decomposes (a) under aerobic conditions, (b) under anaerobic conditions.
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Get started for freeThe standard enthalpies of formation of \(\mathrm{ClO}\) and \(\mathrm{ClO}_{2}\) are 101 and \(102 \mathrm{~kJ} / \mathrm{mol}\), respectively. Using these data and the thermodynamic data in Appendix \(C\), calculate the overall enthalpy change for each step in the following catalytic cycle: $$ \begin{aligned} &\mathrm{ClO}(g)+\mathrm{O}_{3}(g) \longrightarrow \mathrm{ClO}_{2}(g)+\mathrm{O}_{2}(g) \\ &\mathrm{ClO}_{2}(g)+\mathrm{O}(g) \longrightarrow \mathrm{ClO}(g)+\mathrm{O}_{2}(g) \end{aligned} $$ What is the enthalpy change for the overall reaction that results from these two steps?
(a) Write a chemical equation that describes the attack of acid rain on limestone, \(\mathrm{CaCO}_{3}\), (b) If a limestone sculpture were treated to form a surface layer of calcium sulfate, would this help to slow down the effects of acid rain? Explain.
Supposethat on another planet the atmosphere consists of \(17 \% \mathrm{Kr}, 38 \% \mathrm{CH}_{4}\), and \(45 \% \mathrm{O}_{2}\). What is theaverage molar mass at the surface? What is the average molar mass at an altitude at which all the \(\mathrm{O}_{2}\) is photodissociated?
You are working with an artist who has been commissioned to make a sculpture for a big city in the eastern United States. The artist is wondering what material to use to make her sculpture, because she has heard that acid rain in the eastern U.S. might destroy it over time. You take samples of granite, marble, bronze, and other materials, and place them outdoors for a long time in the big city. You periodically examine the appearance and measure the mass of the samples. (a) What observations would lead you to conclude that one, or more, of the materials were well-suited for the sculpture? (b) What chemical process (or processes) is (are) the most likely responsible for any observed changes in the materials? [Section 18.4]
As of the writing of this text, EPA standards limit atmospheric ozone levels in urban environments to 84 ppb. How many moles of ozone would there be in the air above Los Angeles County (area about 4000 square miles; consider a height of \(10 \mathrm{~m}\) above the ground) if ozone was at this concentration?
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