Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
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Get started for freeConsider the ionic compounds KF, NaCl, NaBr, and LiCl. (a) Use ionic radil (Figure 7.8) to estimate the cation-anion distance for each compound. (b) Based on your answer to part (a), arrange these four compounds in order of decreasing lattice energy. (c) Check your predictions in part (b) with the experimental values of lattice energy from Table \(8.1 .\) Are the predictions from ionic radii correct?
Draw the Lewis structures for each of the following ions or molecules. Identify those in which the octet rule is not obeyed; state which atom in each compound does not follow the octet rule; and state, for those atoms, how many electrons surround these atoms: (a) \(\mathrm{PH}_{3},\) (b) AlH_ \(_{3},(\mathbf{c}) \mathrm{N}_{3}^{-}\) (d) \(\mathrm{CH}_{2} \mathrm{Cl}_{2},(\mathbf{e}) \mathrm{SnF}_{6}^{2-}\)
Formic acid has the chemical formula HCOOH. It is a colorless liquid that has a density of 1.220 \(\mathrm{g} / \mathrm{mL}\) . (a) The carbon atom in formic acid is bound to one \(\mathrm{H}\) and both \(\mathrm{O}^{\prime}\) 's. Draw the Lewis structure for formic acid, showing resonance if present. (b) Formic acid can react with NaOH in aqueous solution to produce the formate ion, HCOO- . Write the balanced chemical equation for this reaction. (c) Draw the Lewis structure of the formate ion, showing resonance if present. (d) How many milliliters of a 0.100 M solution of NaOH would it take to completely react with 0.785 \(\mathrm{mL}\) of formic acid?
State whether each of these statements is true or false. (a) The longer the bond, the larger the bond enthalpy. (b) \(C-C\) bonds are stronger than \(C-H\) bonds. (c) A typical single bond length is in the \(5-10\) Ä range. (d) If you break a chemical bond, energy is released.(e) Energy is stored in chemical bonds.
Consider the formate ion, \(\mathrm{HCO}_{2}^{-},\) which is the anion formed when formic acid loses an \(\mathrm{H}^{+}\) ton. The \(\mathrm{H}\) and the two O atoms are bonded to the central \(\mathrm{C}\) atom. (a) Draw the best Lewis structure(s) for this ion. (b) Are resonance structures needed to describe the structure? (c) Would you predict that the \(\mathrm{C}-\mathrm{O}\) bond lengths in the formate ion would be longer or shorter relative to those in \(\mathrm{CO}_{2} ?\)
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