Chapter 23: Problem 17
Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?
Chapter 23: Problem 17
Which type of substance is attracted by a magnetic field, a diamagnetic substance or a paramagnetic substance?
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Get started for freeThe lanthanide contraction explains which of the following periodic trends? (a) The atomic radii of the transitionmetals first decrease and then increase when moving horizontally across each period. (b) When forming ions the period 4 transition metals lose their 4\(s\) electrons before their 3\(d\) electrons. (c) The radii of the period 5 transition metals \((\mathrm{Y}-\mathrm{Cd})\) are very similar to the radii of the period 6 transition metals \((\mathrm{Lu}-\mathrm{Hg}).\)
For a given metal ion and set of ligands, is the crystal-field splitting energy larger for a tetrahedral or an octahedral geometry?
For each of the following metals, write the electronic configuration of the atom and its \(3+\) ion: (a) Fe, (b) Mo, (c) Co. Draw the crystal-field energy- level diagram for the \(d\) orbitals of an octahedral complex, and show the placement of the \(d\) electrons for each \(3+\) ion, assuming a weak-field complex. How many unpaired electrons are there in each case?
How many electrons are in the valence \(d\) orbitals in these transition-metal ions? (a) \(\mathrm{Co}^{3+},(\mathbf{b}) \mathrm{Cu}^{+},(\mathbf{c}) \mathrm{Cd}^{2+},(\mathbf{d}) \mathrm{Os}^{3+}.\)
The most important oxides of iron are magnetite, \(\mathrm{Fe}_{3} \mathrm{O}_{4}\) and hematite, \(\mathrm{Fe}_{2} \mathrm{O}_{3} .\) (a) What are the oxidation states of iron in these compounds? (b) One of these iron oxides is ferrimagnetic, and the other is antiferromagnetic. Which iron oxide is more likely to be ferrimagnetic? Explain.
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