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Indicate whether each of the following statements is true or false: (a) If something is reduced, it is formally losing electrons. (b) A reducing agent gets oxidized as it reacts. (c) An oxidizing agent is needed to convert CO into CO2 .

Short Answer

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(a) False - Reduction means a species is gaining electrons, not losing them. (b) True - A reducing agent gets oxidized as it reacts. (c) True - An oxidizing agent is needed to convert CO to CO2.

Step by step solution

01

(a) Analyzing the statement about reduction and electron loss.

A reduction reaction is one in which a species gains electrons. It's important to remember the mnemonic "LEO says GER" or "Loss of Electrons is Oxidation; Gain of Electrons is Reduction." Thus, the statement is false since a reduction means an electron gain and not loss.
02

(b) Analyzing the statement about reducing agents.

A reducing agent is a substance that reduces other species, meaning it helps other species gain electrons. In doing so, the reducing agent itself loses electrons and gets oxidized. Therefore, the statement is true.
03

(c) Analyzing the statement about converting CO to CO2.

The conversion of CO to CO2 involves adding an oxygen atom to the CO molecule. This process requires an oxidizing agent, which has the ability to remove electrons from another substance. Specifically, it's needed to transfer an oxygen atom (or a part of it) to CO. Thus, the statement is true. #Summary#: We have determined the truthfulness of the following statements: (a) False - Reduction means a species is gaining electrons, not losing them. (b) True - A reducing agent gets oxidized as it reacts. (c) True - An oxidizing agent is needed to convert CO to CO2.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Reduction Definition
In the world of chemistry, reduction is a fundamental concept that involves the gain of electrons by a molecule, atom, or ion. It might sound a bit technical, but think of it as a way for a species to receive electrons. This means that during a reduction reaction, the charge of the species becomes more negative or, in other words, its oxidation state decreases. A mnemonic to help remember this is "LEO says GER," which stands for "Loss of Electrons is Oxidation; Gain of Electrons is Reduction."

Reduction is often paired with oxidation in what's called a redox reaction, where one species is reduced and another is oxidized. You could visualize it as a give-and-take relationship in the exchange of electrons. Interestingly, in biology, reduction doesn't solely focus on electrons; it can also involve the addition of hydrogen to the reduced molecule or loss of oxygen.
Oxidation Definition
Oxidation is the process opposite to reduction. It involves the loss of electrons from a molecule, atom, or ion. Again, it helps to remember the phrase "LEO says GER." Here, "LEO" stands for "Loss of Electrons is Oxidation." This loss of electrons leads to an increase in the oxidation state, meaning the species becomes more positive.

Oxidation can be visualized in everyday examples, such as the rusting of iron, where iron loses electrons to oxygen in the air. Other times, oxidation involves gaining oxygen atoms or losing hydrogen atoms. Like two sides of a coin, oxidation and reduction always occur together in a redox reaction, contributing to many biological and chemical processes. These reactions are critical in industries and natural phenomena, from energy production to cellular respiration in living organisms.
Reducing and Oxidizing Agents
In every redox reaction, there are agents that drive the respective processes of oxidation and reduction. The reducing agent, sometimes called a reductant, facilitates the reduction of another species by donating electrons to it. Interestingly, as it donates electrons, the reducing agent itself gets oxidized. Paper clips rusting away and batteries running low are practical examples where reducing agents play a role.

Conversely, the oxidizing agent, or oxidant, facilitates oxidation by accepting electrons from another species. This process leads to it becoming reduced. A classic example of an oxidizing agent is bleach, which works by stripping electrons away from stains on clothes or surfaces.
  • A strong reducing agent has a high tendency to lose electrons easily, such as lithium or sodium.
  • A strong oxidizing agent readily accepts electrons, such as fluorine or chlorine, known for their high electronegativity.
Understanding the roles of these agents is crucial, as they are indispensable in various chemical reactions, including combustion, metabolism, and even photography.

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Most popular questions from this chapter

A voltaic cell that uses the reaction T3+(aq)+2Cr2+(aq)Tl+(aq)+2Cr3+(aq) has a measured standard cell potential of +1.19V . (a) Write the two half-cell reactions. (b) By using data from Appendix E, determine E red  for the reaction involving Pd. (c) Sketch the voltaic cell, label the anode and cathode, and indicate the direction of electron flow.

(a) Write the half-reaction that occurs at a hydrogen electrode in acidic aqueous solution when it serves as the cathode of a voltaic cell.(b) Write the half-reaction that occurs at a hydrogen electrode in acidic aqueous solution when it serves as the anode of a voltaic cell. (c) What is standard about the standard hydrogen electrode?

A common shorthand way to represent a voltaic cell is anode|anode solution||cathode solution|cathode A double vertical line represents a salt bridge or a porous barrier. A single vertical line represents a change in phase, such as from solid to solution. (a) Write the half-reactions and overall cell reaction represented by Fel Fe 2+Ag+|Ag; calculate the standard cell emf using data in Appendix E. (b) Write the half-reactions and overall cell reaction represented by Zn |Zn2+|H+|H2; calculate the standard cell emf using data in Appendix E and use Pt for the hydrogen electrode. (c) Using the notation just described, represent a cell based on the following reaction: ClO3(aq)+3Cu(s)+6H+(aq)Cl(aq)+3Cu2+(aq)+3H2O(l) Pt is used as an inert electrode in contact with the ClO 3 and Cl. Calculate the standard cell emf given: ClO3(aq)+ 6H+(aq)+6eCl(aq)+3H2O(l);E=1.45V.

Complete and balance the following equations, and identify the oxidizing and reducing agents:  (a) Cr2O72(aq)+I(aq)Cr3+(aq)+IO3(aq) (acidic solution)  (b) MnO4(aq)+CH3OH(aq)Mn2+(aq)+HCOOH(aq) (acidicsolution) (c) I2(s)+OCl(aq)IO3(aq)+Cl(aq) (acidic solution)  (d) As2O3(s)+NO3(aq)H3AsO4(aq)+N2O3(aq)( acidicsolution ) (e) MnO4(aq)+Br(aq)MnO2(s)+BrO3(aq) (basic solution)  (f) Pb(OH)42(aq)+ClO(aq)PbO2(s)+Cl(aq) (basic solution) 

Iron corrodes to produce rust, Fe2O3, but other corrosion products that can form are Fe(O)(OH), iron oxyhydroxide, and magnetite, Fe3O4 . (a) What is the oxidation number of Fe in iron oxyhydroxide, assuming oxygen's oxidation number is 2? (b) The oxidation number for Fe in magnetite was controversial for a long time. If we assume that oxygen's oxidation number is 2, and Fe has a unique oxidation number, what is the oxidation number for Fe in magnetite? (c) It turns out that there are two different kinds of Fe in magnetite that have different oxidation numbers. Suggest what these oxidation numbers are and what their relative stoichiometry must be, assuming oxygen's oxidation number is - 2 .

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