Chapter 20: Problem 14
(a) What is meant by the term reduction? (b) On which side of a reduction half-reaction do the electrons appear? (c) What is meant by the term reductant? (d) What is meant by the term reducing agent?
Chapter 20: Problem 14
(a) What is meant by the term reduction? (b) On which side of a reduction half-reaction do the electrons appear? (c) What is meant by the term reductant? (d) What is meant by the term reducing agent?
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Get started for freeFor a spontaneous reaction \(\mathrm{A}(a q) \rightarrow \mathrm{A}^{-}(a q)+\) \(\mathrm{B}^{+}(a q),\) answer the following questions: (a) If you made a voltaic cell out of this reaction, what half-reaction would be occurring at the cathode, and what half-reaction would be occurring at the anode? (b) Which half-reaction from (a) is higher in potential energy? (c) What is the sign of \(E_{\text { cell }}^{\circ} ?[\) Section 20.3\(]\)
Indicate whether each statement is true or false: (a) The cathode is the electrode at which oxidation takes place. (b) A galvanic cell is another name for a voltaic cell. (c) Electrons flow spontaneously from anode to cathode in a voltaic cell.
Disulfides are compounds that have \(S-\) S bonds, like peroxides have \(O-O\) bonds. Thiols are organic compounds that have the general formula \(R-S H,\) where \(R\) is a generic hydrocarbon. The SH \(^{-}\) is the sulfur counterpart of hydroxide, OH \(^{-} .\) Two thiols can react to make a disulfide, \(\mathrm{R}-\mathrm{S}-\mathrm{S}-\mathrm{R}\) (a) What is the oxidation state of sulfur in a thiol? (b) What is the oxidation state of sulfur in a disulfide? (c) If you react two thiols to make a disulfide, are you oxidizing or reducing the thiols? (d) If you wanted to convert a disulfide to two thiols, should you add a reducing agent or oxidizing agent to the solution? (e) Suggest what happens to the H's in the thiols when they form disulfides.
The capacity of batteries such as the typical AA alkaline battery is expressed in units of milliamp-hours (mAh). An AA alkaline battery yields a nominal capacity of 2850 mAh. (a) What quantity of interest to the consumer is being expressed by the units of mAh? (b) The starting voltage of a fresh alkaline battery is 1.55 V. The voltage decreases during discharge and is 0.80 \(\mathrm{V}\) when the battery has delivered its rated capacity. If we assume that the voltage declines linearly as current is withdrawn, estimate the total maximum electrical work the battery could perform during discharge.
Cytochrome, a complicated molecule that we will represent as CyFe \(^{2+},\) reacts with the air we breathe to supply energy required to synthesize adenosine triphosphate (ATP). The body uses ATP as an energy source to drive other reactions (Section 19.7). At pH 7.0 the following reduction potentials pertain to this oxidation of \(\mathrm{CyFe}^{2+} :\) $$ \begin{aligned} \mathrm{O}_{2}(g)+4 \mathrm{H}^{+}(a q)+4 \mathrm{e}^{-} \longrightarrow 2 \mathrm{H}_{2} \mathrm{O}(l) & E_{\mathrm{red}}^{\circ}=+0.82 \mathrm{V} \\ \mathrm{CyFe}^{3+}(a q)+\mathrm{e}^{-} \longrightarrow \mathrm{CyFe}^{2+}(a q) & E_{\mathrm{red}}^{\circ}=+0.22 \mathrm{V} \end{aligned} $$ (a) What is \(\Delta G\) for the oxidation of CyFe \(^{2+}\) by air? (b) If the synthesis of 1.00 mol of ATP from adenosine diphosphate (ADP) requires a \(\Delta G\) of 37.7 \(\mathrm{kJ}\) , how many moles of ATP are synthesized per mole of \(\mathrm{O}_{2} ?\)
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