Chapter 12: Problem 93
If you want to make a polymer for plastic wrap, should you strive to make a polymer that has a high or low degree of crystallinity?
Chapter 12: Problem 93
If you want to make a polymer for plastic wrap, should you strive to make a polymer that has a high or low degree of crystallinity?
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Get started for freeFor each of these solids, state whether you would expect it to possess metallic properties: (a) TiCl_ \(_{4},(\mathbf{b})\) NiCo alloy, \((\mathbf{c}) \mathrm{W}\) \((\mathbf{d}) \mathrm{Ge},(\mathbf{e}) \mathrm{ScN}\)
Both covalent-network solids and ionic solids can have melting points well in excess of room temperature, and both can be poor conductors of electricity in their pure form. However, in other ways their properties are quite different. $$ \begin{array}{l}{\text { (a) Which type of solid is more likely to dissolve in water? }} \\ {\text { (b) Which type of solid can become a considerably better }} \\ {\text { conductor of electricity via chemical substitution? }}\end{array} $$
Write the chemical equation that represents the formation of $$ \begin{array}{l}{\text { (a) polychloroprene from chloroprene (polychloroprene is }} \\ {\text { used in highway-pavement seals, expansion joints, con- }} \\\ {\text { veyor belts, and wire and cable jackets) }}\end{array} $$ $$ \begin{array}{c}{\mathrm{CH}_{2}=\mathrm{CH}-\underset{\mathrm{C}}{\mathrm{C}=\mathrm{CH}_{2}}} \\\ {\text { Chloroprene }}\end{array} $$ $$ \begin{array}{l}{\text { (b) polyacrylonitrile from acrylonitrile (polyacrylonitrile }} \\ {\text { is used in home furnishings, craft yarns, clothing, and }} \\ {\text { many other items). }}\end{array} $$ $$ \begin{array}{c}{\mathrm{CH}_{2}=\mathrm{CH}} \\ {\mathrm{I}} \\ {\text { Acrylonitrile }}\end{array} $$
What evidence supports the notion that buckyballs are actual molecules and not extended materials? $$ \begin{array}{l}{\text { (a) Buckyballs are made of carbon. }} \\ {\text { (b) Buckyballs have a well-defined atomic structure and }} \\ {\text { molecular weight. }} \\ {\text { (c) Buckyballs have a well-defined melting point. }} \\ {\text { (a) Buckyballs are semiconductors. }} \\ {\text { (e) More than one of the previous choices. }}\end{array} $$
Write a balanced chemical equation for the formation of polymer via a condensation reaction from the monomers succinic acid (HOOCCH \(_{2} \mathrm{CH}_{2} \mathrm{COOH}\) ) and ethylenediamine \(\left(\mathrm{H}_{2} \mathrm{NCH}_{2} \mathrm{CH}_{2} \mathrm{NH}_{2}\right)\)
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