Chapter 12: Problem 19
(a) Draw a picture that represents a crystalline solid at the atomic level. (b) Now draw a picture that represents an amorphous solid at the atomic level.
Chapter 12: Problem 19
(a) Draw a picture that represents a crystalline solid at the atomic level. (b) Now draw a picture that represents an amorphous solid at the atomic level.
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Get started for freeClausthalite is a mineral composed of lead selenide (PbSe). The mineral adopts the rock salt structure. The density of PbSe at \(25^{\circ} \mathrm{C}\) is 8.27 \(\mathrm{g} / \mathrm{cm}^{3} .\) Calculate the length of an edge of the PbSe unit cell.
Covalent bonding occurs in both molecular and covalent network solids. Which of the following statements best explains why these two kinds of solids differ so greatly in their hardness and melting points? $$ \begin{array}{l}{\text { (a) The molecules in molecular solids have stronger covalent bonding than covalent-network solids do. }} \\ {\text { (b) The molecules in molecular solids are held together by weak intermolecular interactions. }}\end{array} $$ $$ \begin{array}{l}{\text { (c) The atoms in covalent-network solids are more polarizable than those in molecular solids. }} \\ {\text { (d) Molecular solids are denser than covalent-network solids. }}\end{array} $$
Indicate whether this statement is true or false: If you want a semiconductor that emits blue light, you could either use a material that has a band gap corresponding to the energy of a blue photon or you could use a material that has a smaller band gap but make an appropriately sized nanoparticle of the same material.
GaAs and GaP make solid solutions that have the same crystal structure as the parent materials, with As and Prandomly distributed throughout the crystal. GaP As \(_{1-x}\) exists for any value of \(x .\) If we assume that the band gap varies linearly with composition between \(x=0\) and \(x=1,\) estimate the band gap for GaP \(_{0.5} \mathrm{As}_{0.5}\) . (GaAs and GaP band gaps are 1.43 \(\mathrm{eV}\) and 2.26 \(\mathrm{eV}\) , respectively.) What wavelength of light does this correspond to?
State whether each of these numbers is a reasonable value for a polymer's molecular weight: 100 amu, \(10,000\) amu, \(100,000\) amu, \(1,000,000\) amu?
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