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(a) How high in meters must a column of glycerol be to exert a pressure equal to that of a \(760-\mathrm{mm}\) column of mercury? The density of glycerol is 1.26 \(\mathrm{g} / \mathrm{mL}\) , whereas that of mercury is 13.6 \(\mathrm{g} / \mathrm{mL}\) . (b) What pressure, in atmospheres, is exerted on the body of a diver if she is 15 ft below the surface of the water when the atmospheric pressure is 750 torr? Assume that the density of the water is \(1.00 \mathrm{g} / \mathrm{cm}^{3}=1.00 \times 10^{3} \mathrm{kg} / \mathrm{m}^{3} .\) The gravitational constant is \(9.81 \mathrm{m} / \mathrm{s}^{2},\) and \(1 \mathrm{Pa}=1 \mathrm{kg} / \mathrm{m}-\mathrm{s}^{2} .\)

Short Answer

Expert verified
(a) To find the height of the glycerol column exerting the same pressure as a 760-mm column of mercury, we use the formula \( h_{glycerol} = \frac{Pressure_{Hg}}{Density_{glycerol} \times g} \). After calculation, we get \( h_{glycerol} \approx 8.17 \mathrm{m} \). (b) The total pressure exerted on the diver is the sum of the atmospheric pressure and the pressure due to the water column. Calculating the total pressure, we get \(Total Pressure_{atm} \approx 1.62 \) atmospheres.

Step by step solution

01

(a) Calculate the pressure of a 760-mm column of mercury

To find the pressure of a 760-mm column of mercury, we can use the formula, \( Pressure = Density \times g \times h \), where h is the height of the column in meters. Convert 760 mm to meters: \( h_{Hg} = 760 \frac{mm}{1} \times \frac{1m}{1000mm} = 0.76 \mathrm{m} \). So the pressure of the mercury column can be calculated as \( Pressure_{Hg} = 13.6 \frac{g}{mL} \times \frac{1000g}{1kg} \times 9.81 \frac{m}{s^{2}} \times 0.76 m \).
02

(a) Calculate the height of the glycerol column

We need to set the pressure of the glycerol column equal to the pressure of the mercury column. The equation becomes, \(Pressure_{Hg} = Density_{glycerol} \times g \times h_{glycerol}\). Rearrange the equation to solve for \(h_{glycerol}\): \( h_{glycerol} = \frac{Pressure_{Hg}}{Density_{glycerol} \times g} \). Substitute the known values and solve for \(h_{glycerol}\).
03

(b) Convert 15 ft to meters

To find the pressure exerted on the body of the diver, we first need to convert the given height from feet to meters. \(height_{water} = 15 \frac{ft}{1} \times \frac{0.3048m}{1ft} = 4.572 \mathrm{m}\).
04

(b) Convert 750 torr to Pascals

To add the atmospheric pressure to the pressure due to the water column, we need to convert 750 torr into Pascals. \(Pressure_{atm} = 750 \frac{torr}{1} \times \frac{101325 Pa}{760 torr} \).
05

(b) Calculate the pressure due to the water column

Using the formula for pressure, \( Pressure_{water} = Density_{water} \times g \times height_{water} \), we can calculate the pressure exerted by the water column. \( Pressure_{water} = 1000 \frac{kg}{m^3} \times 9.81 \frac{m}{s^2} \times 4.572 m \).
06

(b) Find the total pressure on the diver

To find the total pressure exerted on the diver, we need to add the atmospheric pressure to the pressure due to the water column: \(Total Pressure = Pressure_{atm} + Pressure_{water}\).
07

(b) Convert total pressure to atmospheres

Finally, we want the total pressure in atmospheres. Convert the total pressure from Pascals to atmospheres using the conversion factor: \( Total Pressure_{atm} = \frac{Total Pressure}{101325 Pa} \).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Density
Density is a fundamental concept used to describe how much mass is contained in a specific volume of a substance. It is typically expressed in units like grams per milliliter (g/mL) or kilograms per cubic meter (kg/m³). The formula used to calculate density is simple:
  • Density (\(d\)) = Mass (\(m\)) / Volume (\(V\)).
This characteristic property is crucial when calculating pressures exerted by different materials, like liquids. As seen in the exercise, different substances, such as glycerol and mercury, have varying densities that directly affect pressure. For instance, mercury is much denser than glycerol, which means a shorter column of mercury will exert the same pressure as a much taller column of glycerol.
Understanding density can help in comprehending other phenomena, such as buoyancy, where objects with varying densities will float or sink when placed in a fluid.
Pressure Conversion
Pressure is a force applied over a surface area and is often expressed in various units, such as atm (atmospheres), torr, or Pa (Pascals). Thus, understanding pressure conversion is essential, especially when solving problems involving different scales like in the given exercise.
  • 1 atm = 760 torr = 101325 Pa.
In the exercise, we converted 750 torr into Pascals to combine atmospheric pressure with the liquid pressure conveniently. This resulted in the formula:
  • \[Pressure_{atm} = 750 \frac{torr}{1} \times \frac{101325 Pa}{760 torr} \]
Proper conversion enables accurate calculations and understanding, especially when different systems or scientific fields require specific units. Always remember the key conversion factors!
Pressure Exerted by Liquids
The pressure exerted by a liquid in a column depends on its density, the gravitational acceleration, and the height of the liquid column. The formula to determine this pressure is:
  • Pressure = Density \( \times \) Gravitational constant \( \times \) Height.
In the exercise, this formula helped us find pressures for mercury and glycerol columns. Liquids exert pressure equally in all directions, increasing with depth. This principle is why the diver in the exercise experiences additional pressure from the water column above them in addition to atmospheric pressure.
Such calculations are vital for engineering, fluid mechanics, and atmospheric sciences, providing insight into how different factors affect the pressure a specific liquid exerts.
Gravitational Constant
The gravitational constant (usually denoted by \(g\)) on Earth's surface is approximately \(9.81 \ m/s^2\). It plays a crucial role in fluid pressure calculations since gravity influences how much force a liquid exerts.
  • In the pressure formula ( \(Pressure = Density \times g \times Height\)), \(g\) gives the acceleration due to gravity.
In the problem, this constant allows you to understand how gravity pulls the fluid downward, causing it to exert pressure.
Without considering the gravitational constant, one could overlook how gravity affects the system's dynamics. This constant is essential for many calculations involving weight, force, and potential energy.

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Most popular questions from this chapter

An herbicide is found to contain only \(\mathrm{C}, \mathrm{H}, \mathrm{N},\) and Cl. The complete combustion of a 100.0 -mg sample of the herbicide in excess oxygen produces 83.16 \(\mathrm{mL}\) of \(\mathrm{CO}_{2}\) and 73.30 \(\mathrm{mL}\) of \(\mathrm{H}_{2} \mathrm{O}\) vapor expressed at STP. A separate analysis shows that the sample also contains 16.44 \(\mathrm{mg}\) of Cl. (a) Determine the percentage of the composition of the substance. ( b) Calculate its empirical formula. (c) What other information would you need to know about this compound to calculate its true molecular formula?

At constant pressure, the mean free path \((\lambda)\) of a gas molecule is directly proportional to temperature. At constant temperature, \(\lambda\) is inversely proportional to pressure. If you compare two different gas molecules at the same temperature and pressure, \(\lambda\) is inversely proportional to the square of the diameter of the gas molecules. Put these facts together to create a formula for the mean free path of a gas molecule with a proportionality constant (call it \(R_{\text { mfp }}\) , like the ideal-gas constant) and define units for \(R_{\operatorname{mfp}}\) .

Chlorine dioxide gas \(\left(\mathrm{ClO}_{2}\right)\) is used as a commercial bleaching agent. It bleaches materials by oxidizing them. In the course of these reactions, the \(\mathrm{ClO}_{2}\) is itself reduced. (a) What is the Lewis structure for \(\mathrm{ClO}_{2} ?\) (b) Why do you think that \(\mathrm{ClO}_{2}\) is reduced so readily? (c) When a \(\mathrm{ClO}_{2}\) molecule gains an electron, the chlorite ion, \(\mathrm{ClO}_{2}^{-},\) forms. Draw the Lewis structure for \(\mathrm{ClO}_{2}^{-} .\) (d) Predict the \(\mathrm{O}-\mathrm{Cl}-\mathrm{O}\) bond angle in the \(\mathrm{ClO}_{2}^{-}\) ion. (e) One method of preparing \(\mathrm{ClO}_{2}\) is by the reaction of chlorine and sodium chlorite: $$\mathrm{Cl}_{2}(g)+2 \mathrm{NaClO}_{2}(s) \longrightarrow 2 \mathrm{ClO}_{2}(g)+2 \mathrm{NaCl}(s)$$ If you allow 15.0 \(\mathrm{g}\) of \(\mathrm{NaClO}_{2}\) to react with 2.00 \(\mathrm{L}\) of chlorine gas at a pressure of 1.50 atm at \(21^{\circ} \mathrm{C},\) how many grams of \(\mathrm{ClO}_{2}\) can be prepared?

Ammonia and hydrogen chloride react to form solid ammonium chloride: $$\mathrm{NH}_{3}(g)+\mathrm{HCl}(g) \longrightarrow \mathrm{NH}_{4} \mathrm{Cl}(s)$$ Two 2.00 -L flasks at \(25^{\circ} \mathrm{C}\) are connected by a valve, as shown in the drawing. One flask contains 5.00 \(\mathrm{g}\) of \(\mathrm{NH}_{3}(g),\) and the other contains 5.00 \(\mathrm{g}\) of \(\mathrm{HCl}(g) .\) When the valve is opened, the gases react until one is completely consumed. (a) Which gas will remain in the system after the reaction is complete? (b) What will be the final pressure of the system after the reaction is complete? (Neglect the volume of the ammonium chloride formed.) (c) What mass of ammonium chloride will be formed?

Hydrogen gas is produced when zinc reacts with sulfuric acid: $$\mathrm{Zn}(s)+\mathrm{H}_{2} \mathrm{SO}_{4}(a q) \longrightarrow \mathrm{ZnSO}_{4}(a q)+\mathrm{H}_{2}(g)$$ If 159 \(\mathrm{mL}\) of wet \(\mathrm{H}_{2}\) is collected over water at \(24^{\circ} \mathrm{C}\) and a barometric pressure of 738 torr, how many grams of Zn have been consumed? (The vapor pressure of water is tabulated in Appendix B.)

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