Chapter 9: Problem 53
Shown here are three pairs of hybrid orbitals, with each set at a characteristic angle. For each pair, determine the type of hybridization, if any, that could lead to hybrid orbitals at the specified angle.
Chapter 9: Problem 53
Shown here are three pairs of hybrid orbitals, with each set at a characteristic angle. For each pair, determine the type of hybridization, if any, that could lead to hybrid orbitals at the specified angle.
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Get started for freePlace the following molecules and ions in order from smallest to largest bond order: \(\mathrm{H}_{2}^{+}, \mathrm{B}_{2}, \mathrm{~N}_{2}^{+}, \mathrm{F}_{2}^{+}\), and \(\mathrm{Ne}_{2}\).
(a) Explain why the following ions have different bond angles: \(\mathrm{ClO}_{2}^{-}\)and \(\mathrm{NO}_{2}^{-}\). Predict the bond angle in each case. (b) Explain why the \(\mathrm{XeF}_{2}\) molecule is linear.
(a) Which geometry and central atom hybridization would you expect in the series \(\mathrm{BH}_{4}^{-}, \mathrm{CH}_{4}, \mathrm{NH}_{4}^{+}\)? (b) What would you expect for the magnitude and direction of the bond dipoles in this series? (c) Write the formulas for the analogous species of the elements of period 3 ; would you expect them to have the same hybridization at the central atom?
(a) What does the term paramagnetism mean? (b) How can one determine experimentally whether a substance is paramagnetic? (c) Which of the following ions would you expect to be paramagnetic: \(\mathrm{O}_{2}^{+}, \mathrm{N}_{2}{ }^{2-}, \mathrm{Li}_{2}^{+}, \mathrm{O}_{2}{ }^{2-}\) ? For those ions that are paramagnetic, determine the number of unpaired electrons.
How does a trigonal pyramid differ from a tetrahedron so far as molecular geometry is concerned?
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