Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
Chapter 8: Problem 11
Consider the element silicon, Si. (a) Write its electron configuration. (b) How many valence electrons does a silicon atom have? (c) Which subshells hold the valence electrons?
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Get started for freeWrite the Lewis symbol for atoms of each of the following elements: (a) \(\mathrm{Al}\), (b) \(\mathrm{Br}\), (c) \(\mathrm{Ar}\), (d) \(\mathrm{Sr}\).
The following three Lewis structures can be drawn for \(\mathrm{N}_{2} \mathrm{O}\) : \(: \mathrm{N} \equiv \mathrm{N}-\ddot{\mathrm{O}}: \longleftrightarrow: \ddot{\mathrm{N}}-\mathrm{N} \equiv \mathrm{O}: \longleftrightarrow: \ddot{\mathrm{N}}=\mathrm{N}=\ddot{\mathrm{O}}:\) (a) Using formal charges, which of these three resonance forms is likely to be the most important? (b) The \(\mathrm{N}-\mathrm{N}\) bond length in \(\mathrm{N}_{2} \mathrm{O}\) is \(1.12 \AA\), slightly longer than a typical \(\mathrm{N} \equiv \mathrm{N}\) bond; and the \(\mathrm{N}-\mathrm{O}\) bond length is \(1.19 \AA\) Ä, slightly shorter than a typical bond (see Table 8.5). Based on these data, which resonance structure best represents \(\mathrm{N}_{2} \mathrm{O}\) ?
Predict the chemical formula of the ionic compound formed between the following pairs of elements: (a) \(\mathrm{Al}\) and \(\mathrm{F}\), (b) \(\mathrm{K}\) and \(\mathrm{S}\), (c) \(\mathrm{Y}\) and \(\mathrm{O}\), (d) \(\mathrm{Mg}\) and \(\mathrm{N}\).
The compound chloral hydrate, known in detective stories as knockout drops, is composed of \(14.52 \% \mathrm{C}, 1.83 \% \mathrm{H}\), \(64.30 \% \mathrm{Cl}\), and \(13.35 \% \mathrm{O}\) by mass, and has a molar mass of \(165.4 \mathrm{~g} / \mathrm{mol}\). (a) What is the empirical formula of this substance? (b) What is the molecular formula of this substance? (c) Draw the Lewis structure of the molecule, assuming that the \(\mathrm{Cl}\) atoms bond to a single \(\mathrm{C}\) atom and that there are \(\mathrm{C}-\mathrm{C}\) bond and two \(\mathrm{C}-\mathrm{O}\) bonds in the compound.
You and a partner are asked to complete a lab entitled " \(\mathrm{Ox}\) ides of Ruthenium" that is scheduled to extend over two lal periods. The first lab, which is to be completed by your part ner, is devoted to carrying out compositional analysis. In th second lab, you are to determine melting points. Upon going to lab you find two unlabeled vials, one containing a soft yel low substance and the other a black powder. You also find the following notes in your partner's notebook-Compounc \(1: 76.0 \% \mathrm{Ru}\) and \(24.0 \% \mathrm{O}\) (by mass), Compound \(2: 61.2 \% \mathrm{R}\) and \(38.8 \% \mathrm{O}\) (by mass). (a) What is the empirical formula for Compound 1 ? (b) What is the empirical formula for Compound 2? Upon determining the melting points of these two compounds, you find that the yellow compound melts at \(25^{\circ} \mathrm{C}\), while the black powder does not melt up to the maximum temperature o. your apparatus, \(1200^{\circ} \mathrm{C}\). (c) What is the identity of the yellow compound? (d) What is the identity of the black compound? (e) Which compound is molecular? (f) Which compound is ionic?
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