Chapter 7: Problem 38
Write equations that show the process for (a) the first two ionization energies of lead and (b) the fourth ionization energy of zirconium.
Chapter 7: Problem 38
Write equations that show the process for (a) the first two ionization energies of lead and (b) the fourth ionization energy of zirconium.
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Compare the elements bromine and chlorine with respect to the following properties: (a) electron configuration, (b) most common ionic charge, (c) first ionization energy, (d) reactivity toward water, (e) electron affinity, (f) atomic radius. Account for the differences between the two elements.
Note from the following table that there is a significant increase in atomic radius upon moving from \(\mathrm{Y}\) to La whereas the radii of \(\mathrm{Zr}\) to \(\mathrm{Hf}\) are the same. Suggest an explanation for this effect. $$ \begin{array}{llll} \hline & {\text { Atomic Radii (Å) }} \\ \hline \mathrm{Sc} & 1.70 & \mathrm{Ti} & 1.60 \\ \mathrm{Y} & 1.90 & \mathrm{Zr} & 1.75 \\ \mathrm{La} & 2.07 & \text { Hf } & 1.75 \\ \hline \end{array} $$
The first ionization energy and electron affinity of Ar are both positive values. (a) What is the significance of the positive value in each case? (b) What are the units of electron affinity?
Potassium superoxide, \(\mathrm{KO}_{2}\), is often used in oxygen masks (such as those used by firefighters) because \(\mathrm{KO}_{2}\) reacts with \(\mathrm{CO}_{2}\) to release molecular oxygen. Experiments indicate that \(2 \mathrm{~mol}\) of \(\mathrm{KO}_{2}(s)\) react with each mole of \(\mathrm{CO}_{2}(g)\). (a) The products of the reaction are \(\mathrm{K}_{2} \mathrm{CO}_{3}(s)\) and \(\mathrm{O}_{2}(g)\). Write a balanced equation for the reaction between \(\mathrm{KO}_{2}(s)\) and \(\mathrm{CO}_{2}(g)\). (b) Indicate the oxidation number for each atom involved in the reaction in part (a). What elements are being oxidized and reduced? (c) What mass of \(\mathrm{KO}_{2}(s)\) is needed to consume \(18.0 \mathrm{~g} \mathrm{CO}_{2}(\mathrm{~g})\) ? What mass of \(\mathrm{O}_{2}(g)\) is produced during this reaction?
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