Chapter 5: Problem 93
An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?
Chapter 5: Problem 93
An aluminum can of a soft drink is placed in a freezer. Later, you find that the can is split open and its contents frozen. Work was done on the can in splitting it open. Where did the energy for this work come from?
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Get started for freeConsider the following reaction: $$ 2 \mathrm{Mg}(s)+\mathrm{O}_{2}(g) \longrightarrow 2 \mathrm{MgO}(s) \quad \Delta H=-1204 \mathrm{~kJ} $$ (a) Is this reaction exothermic or endothermic? (b) Calculate the amount of heat transferred when \(3.55 \mathrm{~g}\) of \(\mathrm{Mg}(s)\) reacts at constant pressure. (c) How many grams of \(\mathrm{MgO}\) are produced during an enthalpy change of \(-234 \mathrm{~kJ}\) ? (d) How many kilojoules of heat are absorbed when \(40.3 \mathrm{~g}\) of \(\mathrm{MgO}(s)\) is decomposed into \(\mathrm{Mg}(s)\) and \(\mathrm{O}_{2}(g)\) at constant pressure?
Gasoline is composed primarily of hydrocarbons, including many with eight
carbon atoms, called octanes. One of the cleanestburning octanes is a compound
called 2,3,4-trimethylpentane, which has the following structural formula:
The decomposition of \(\mathrm{Ca}(\mathrm{OH})_{2}(s)\) into \(\mathrm{CaO}(s)\) and \(\mathrm{H}_{2} \mathrm{O}(g)\) at constant pressure requires the addition of \(109 \mathrm{~kJ}\) of heat per mole of \(\mathrm{Ca}(\overline{\mathrm{OH}})_{2}\). (a) Write a balanced thermochemical equation for the reaction. (b) Draw an enthalpy diagram for the reaction.
Consider the combustion of liquid methanol, \(\mathrm{CH}_{3} \mathrm{OH}(l)\) : $$ \begin{array}{r} \mathrm{CH}_{3} \mathrm{OH}(l)+\frac{3}{2} \mathrm{O}_{2}(g) \longrightarrow \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{O}(l) \\ \Delta H=-726.5 \mathrm{~kJ} \end{array} $$ (a) What is the enthalpy change for the reverse reaction? (b) Balance the forward reaction with whole-number coefficients. What is \(\Delta H\) for the reaction represented by this equation? (c) Which is more likely to be thermodynamically favored, the forward reaction or the reverse reaction? (d) If the reaction were written to produce \(\mathrm{H}_{2} \mathrm{O}(g)\) instead of \(\mathrm{H}_{2} \mathrm{O}(l)\), would you expect the magnitude of \(\Delta H\) to increase, decrease, or stay the same? Explain.
(a) Under what condition will the enthalpy change of a process equal the amount of heat transferred into or out of the system? (b) During a constant- pressure process, the system releases heat to the surroundings. Does the enthalpy of the system increase or decrease during the process? (c) In a constant-pressure process, \(\Delta H=0\). What can you conclude about \(\Delta E, q\), and \(w\) ?
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