Chapter 24: Problem 45
Draw the molecular structure for (a) an aldehyde that is an isomer of acetone, (b) an ether that is an isomer of 1-propanol.
Chapter 24: Problem 45
Draw the molecular structure for (a) an aldehyde that is an isomer of acetone, (b) an ether that is an isomer of 1-propanol.
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Get started for free(a) Are \(\alpha\)-glucose and \(\beta\)-glucose enantiomers? (b) Show the condensation of two glucose molecules to form a disaccharide with an \(\alpha\) linkage. (c) Repeat part (b) but with a \(\beta\) linkage.
Predict the ideal values for the bond angles about each carbon atom in the following molecule. Indicate the hybridization of orbitals for each carbon. $$ \mathrm{CH}_{3} \mathrm{CCCH}_{2} \mathrm{COOH} $$
A typical amino acid with one amino group and one carboxylic acid group, such as serine, can exist in water in several ionic forms. (a) Suggest the forms of the amino acid at low pH and at high \(\mathrm{pH}\). (b) Amino acids generally have two \(\mathrm{p} K_{a}\) values, one in the range of 2 to 3 and the other in the range of 9 to 10. Serine, for example, has \(\mathrm{pK} K_{4}\) values of \(2.19\) and \(9.21\). Using species such as acetic acid and ammonia as models, suggest the origin of the two \(\mathrm{pK}_{\mathrm{a}}\) values. (c) Glutamic acid is an amino acid that has three \(\mathrm{pK}_{a}\) ' \(\times 2.10,4.07\), and 9.47. Draw the structure of glutamic acid, and assign each \(\mathrm{p} K_{a}\) to the appropriate part of the molecule. (d) An unknown amino acid is titrated with strong base, producing the following titration curve. Which amino acids are likely candidates for the unknown?
(a) Draw the condensed structure of the tripeptide Gly-GlyHis. (b) How many different tripeptides can be made from the amino acids glycine and histidine? Give the abbreviations for each of these tripeptides, using the three-letter and one-letter codes for the amino acids.
An unknown organic compound is found on elemental analysis to contain \(68.1 \%\) carben, \(13.7 \%\) hydrogen, and \(18.2 \%\) oxygen by mass. It is slightly soluble in water. Upon careful oxidation it is converted into a compound that behaves chemically like a ketone and contains \(69.7 \%\) carbon, \(11.7 \%\) hydrogen, and \(18.6 \%\) oxygen by mass, Indicate twe or more reasonable structures for the unknown.
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