Chapter 23: Problem 18
Which type of magnetic material cannot be used to make permanent magnets, a ferromagnetic substance, an antiferromagnetic substance, or a ferrimagnetic substance?
Chapter 23: Problem 18
Which type of magnetic material cannot be used to make permanent magnets, a ferromagnetic substance, an antiferromagnetic substance, or a ferrimagnetic substance?
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Get started for freeThe complex \(\left[\mathrm{Mn}\left(\mathrm{NH}_{3}\right)_{6}\right]^{2+}\) contains five unpaired electrons. Sketch the energy-level diagram for the \(d\) arbitals, and indicate the placement of electrons for this complex ion. Is the ion a high-spin or a low-spin complex?
Which transition metal atom is present in each of the following biologically important molecules: (a) hemoglobin, (b) chlorophylls, (c) siderophores.
The lobes of which \(d\) orbitals point directly between the ligands in (a) octahedral geometry, (b) tetrahedral geometry?
Indicate the likely coordination number of the metal in each of the following complexes (a) \(\left[\mathrm{Rh}(\text { bipy })_{3}\right]\left(\mathrm{NO}_{3}\right)_{3}\) (b) \(\mathrm{Na}_{4}\left[\mathrm{Co}\left(\mathrm{C}_{2} \mathrm{O}_{4}\right)_{2} \mathrm{Cl}_{2}\right]\) (c) \(\left[\mathrm{Cr}(0 \text {-phen })_{3}\right]\left(\mathrm{CH}_{3} \mathrm{COO}\right)_{3}\) (d) \(\mathrm{Na}_{2}[\mathrm{Co}(\mathrm{EDTA}) \mathrm{Br}]\)
Give the number of (valence) \(d\) electrons associated with the central metal ion in each of the following complexes: (a) \(\mathrm{K}_{3}\left[\mathrm{Fe}(\mathrm{CN})_{6}\right]\), (b) \(\left[\mathrm{Mn}\left(\mathrm{H}_{2} \mathrm{O}\right)_{6}\right]\left(\mathrm{NO}_{3}\right)_{2}\) (c) \(\mathrm{Na}\left[\mathrm{Ag}(\mathrm{CN})_{2}\right]\), (d) \(\left[\mathrm{Cr}\left(\mathrm{NH}_{3}\right)_{4} \mathrm{Br}_{2}\right] \mathrm{ClO}_{4}\), (c) \([\mathrm{Sr}(\mathrm{EDTA})]^{2-}\) -
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