Chapter 22: Problem 23
Write a balanced equation for the preparation of \(\mathrm{H}_{2}\) using (a) \(\mathrm{Mg}\) and an acid, (b) carbon and steam, (c) methane and steam.
Chapter 22: Problem 23
Write a balanced equation for the preparation of \(\mathrm{H}_{2}\) using (a) \(\mathrm{Mg}\) and an acid, (b) carbon and steam, (c) methane and steam.
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Get started for free(a) The \(\mathrm{P}_{4}, \mathrm{P}_{4} \mathrm{O}_{6}\) and \(\mathrm{P}_{4} \mathrm{O}_{10}\) molecules have a common structural feature of four \(\mathrm{P}\) atoms arranged in a tetrahedron (Figures \(22.27\) and 22.28). Does this mean that the bonding between the \(\mathrm{P}\) atoms is the same in all these cases? Explain. (b) Sodium trimetaphosphate \(\left(\mathrm{Na}_{3} \mathrm{P}_{3} \mathrm{O}_{9}\right)\) and sodium tetrametaphosphate \(\left(\mathrm{Na}_{4} \mathrm{P}_{4} \mathrm{O}_{12}\right)\) are used as water-softening agents. They contain cyclic \(\mathrm{P}_{3} \mathrm{O}_{9}{ }^{3-}\) and \(\mathrm{P}_{4} \mathrm{O}_{12}{ }^{4-}\) ions, respectively. Propose reasonable structures for these ions.
Both dimethylhydrazine, \(\left(\mathrm{CH}_{3}\right)_{2} \mathrm{NNH}_{2}\), and methylhydrazine, \(\mathrm{CH}_{3} \mathrm{NHNH}_{2}\), have been used as rocket fuels. When dinitrogen tetroxide \(\left(\mathrm{N}_{2} \mathrm{O}_{4}\right)\) is used as the oxidizer, the products are \(\mathrm{H}_{2} \mathrm{O}, \mathrm{CO}_{2}\), and \(\mathrm{N}_{2}\). If the thrust of the rocket depends on the volume of the products produced, which of the substituted hydrazines produces a greater thrust per gram total mass of oxidizer plus fuel? (Assume that both fuels generate the same temperature and that \(\mathrm{H}_{2} \mathrm{O}(g)\) is formed.)
Give the chemical formula for (a) carbonic acid, (b) sodium cyanide, (c) potassium hydrogen carbonate, (d) acetylene, (e) iron pentacarbonyl.
Explain each of the following observations: (a) At room temperature \(\mathrm{I}_{2}\) is a solid, \(\mathrm{Br}_{2}\) is a liquid, and \(\mathrm{Cl}_{2}\) and \(\mathrm{F}_{2}\) are both gases. (b) \(\mathrm{F}_{2}\) cannot be prepared by electrolytic oxidation of aqueous \(\mathrm{F}^{-}\) solutions. (c) The boiling point of HF is much higher than those of the other hydrogen halides. (d) The halogens decrease in oxidizing power in the order \(\mathrm{F}_{2}>\mathrm{Cl}_{2}>\mathrm{Br}_{2}>\mathrm{I}_{2}\).
Identify cach of the following elements as a metal, nonmetal, or metalloid: (a) phosphorus, (b) strontium, (c) manganese, (d) sclenium, (c) sodium, (f) krypton.
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