Chapter 22: Problem 21
Give a reason why hydrogen might be placed along with the group lA elements of the periodic table.
Chapter 22: Problem 21
Give a reason why hydrogen might be placed along with the group lA elements of the periodic table.
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Get started for freeWrite a balanced equation for each of the following reactions: (a) Burning magnesium metal in a carbon dioxide atmosphere reduces the \(\mathrm{CO}_{2}\) to carbon. (b) In photosynthesis, solar energy is used to produce glucose \(\left(\mathrm{C}_{6} \mathrm{H}_{12} \mathrm{O}_{6}\right)\) and \(\mathrm{O}_{2}\) from carbon dioxide and water. (c) When carbonate salts dissolve in water, they produce basic solutions.
The maximum allowable concentration of \(\mathrm{H}_{2} \mathrm{~S}(\mathrm{~g})\) in air is \(20 \mathrm{mg}\) per kilogram of air (20 ppm by mass). How many grams of FeS would be required to react with hydrochloric acid to produce this concentration at \(1.00\) atm and \(25^{\circ} \mathrm{C}\) in an average room measuring \(12 \mathrm{ft} \times 20 \mathrm{ft} \times 8 \mathrm{ft}\) ? (Under these conditions, the average molar mass of air is \(29.0 \mathrm{~g} / \mathrm{mol}\).)
(a) What is the characteristic geometry about silicon in all silicate minerals? (b) Metasilicic acid has the empirical formula \(\mathrm{H}_{2} \mathrm{SiO}_{3}\). Which of the structures shown in Figure \(22.34\) would you expect metasilicic acid to have? 22.76 Speculate as to why carbon forms carbonate rather than silicate analogs.
Write balanced equations for each of the following reactions. (a) When mercury(II) oxide is heated, it decomposes to form \(\mathrm{O}_{2}\) and mercury metal. (b) When copper(II) nitrate is heated strongly, it decomposes to form copper(II) oxide, nitrogen dioxide, and oxygen. (c) Lead(II) sulfide, \(\mathrm{PbS}(s)\), reacts with ozone to form \(\mathrm{PbSO}_{4}(s)\) and \(\mathrm{O}_{2}(g)\). (d) When heated in air, \(\mathrm{ZnS}(s)\) is converted to \(\mathrm{ZnO}\). (e) Potassium peroxide reacts with \(\mathrm{CO}_{2}(g)\) to give potassium carbonate and \(\mathrm{O}_{2}\) (f) Oxygen is converted to ozone in the upper atmosphere.
Explain each of the following observations: (a) At room temperature \(\mathrm{I}_{2}\) is a solid, \(\mathrm{Br}_{2}\) is a liquid, and \(\mathrm{Cl}_{2}\) and \(\mathrm{F}_{2}\) are both gases. (b) \(\mathrm{F}_{2}\) cannot be prepared by electrolytic oxidation of aqueous \(\mathrm{F}^{-}\) solutions. (c) The boiling point of HF is much higher than those of the other hydrogen halides. (d) The halogens decrease in oxidizing power in the order \(\mathrm{F}_{2}>\mathrm{Cl}_{2}>\mathrm{Br}_{2}>\mathrm{I}_{2}\).
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