Chapter 18: Problem 58
Discuss how catalysts can make processes more energy efficient.
Chapter 18: Problem 58
Discuss how catalysts can make processes more energy efficient.
All the tools & learning materials you need for study success - in one app.
Get started for freeThe degradation of \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) (an \(\mathrm{HFC}\) ) by \(\mathrm{OH}\) radicals in the troposphere is first order in each reactant and has a rate constant of \(k=1.6 \times 10^{8} \mathrm{M}^{-1} \mathrm{~s}{ }^{-1}\) at \(4^{\circ} \mathrm{C}\). If the tropospheric concentrations of \(\mathrm{OH}\) and \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) are \(8.1 \times 10^{3}\) and \(6.3 \times 10^{3}\) molecules/ \(/ \mathrm{cm}^{3}\), respectively, what is the rate of reaction at this temperature in \(M / s\) ?
What properties make a substance a good coagulant for water purification?
Alcohol-based fuels for automobiles lead to the production of formaldehyde \(\left(\mathrm{CH}_{2} \mathrm{O}\right)\) in exhaust gases. Formaldehyde undergoes photodissociation, which contributes to photochemical smog: $$ \mathrm{CH}_{2} \mathrm{O}+h_{\mathrm{w}} \longrightarrow \mathrm{CHO}+\mathrm{H} $$ The maximum wavelength oflight that can cause this reaction is \(335 \mathrm{~nm}\). (a) In what part of the electromagnetic spectrum is light with this wavelength found? (b) What is the maximum strength of a bond, in \(\mathrm{kJ} / \mathrm{mol}\), that can be broken by absorption of a photon of 335 -nm light? (c) Compare your answer from part (b) to the appropriate value from Table 8.4. What do you conclude about \(\mathrm{C}-\mathrm{H}\) bond energy in formaldehyde? (d) Write out the formaldehyde photodissociation reaction. showing Lewis-dot structures.
In \(\mathrm{CF}_{3} \mathrm{Cl}\) the \(\mathrm{C}-\mathrm{Cl}\) bond- dissociation energy is \(339 \mathrm{~kJ} / \mathrm{mol}\), In \(\mathrm{CCl}_{4}\) the \(\mathrm{C}-\mathrm{Cl}\) bond-dissociation energy is \(293 \mathrm{~kJ} / \mathrm{mol}\). What is the range of wavelengths of photons that can cause \(\mathrm{C}\) - Cl bond rupture in one molecule but not in the other?
Why is rainwater naturally acidic, even in the absence of polluting gases such as \(\mathrm{SO}_{2}\) ?
What do you think about this solution?
We value your feedback to improve our textbook solutions.