Chapter 18: Problem 54
What properties make a substance a good coagulant for water purification?
Chapter 18: Problem 54
What properties make a substance a good coagulant for water purification?
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The precipitation of \(\mathrm{A}(\mathrm{OH})_{3}\left(K_{s p}=1.3 \times 10^{-3}\right)\) is sometimes used to purify water. (a) Estimate the pH at which precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\) will begin if \(5.0 \mathrm{lb}^{\text {of }} \mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) is added to \(2000 \mathrm{gal}\) of water. (b) Approximately how many pounds of \(\mathrm{CaO}\) must be added to the water to achieve this pH?
In 1986 an electrical power plant in Taylorsville, Georgia, burned \(8,376,726\) tons of coal, a national recerd at that time. (a) Assuming that the coal was \(83 \%\) carbon and \(2.5 \%\) sulfur and that combustion was complete, calculate the number of tons of carbon dioxide and sulfur dioxide produced by the plant during the year. (b) If \(55 \%\) of the \(\mathrm{SO}_{2}\) could be removed by reaction with powdered \(\mathrm{CaO}\) to form \(\mathrm{CaSO}_{3}\), how many tons of \(\mathrm{CaSO}_{3}\) would be produced?
A first-stage recovery of magnesium from seawater is precipitation of \(\mathrm{Mg}(\mathrm{OH})_{2}\) with \(\mathrm{CaO}\) : $$ \mathrm{Mg}^{2+}(a q)+\mathrm{CaO}(s)+\mathrm{H}_{2} \mathrm{O}(t) \longrightarrow \mathrm{Mg}(\mathrm{OH})_{2}(s)+\mathrm{Ca}^{2+}(a q) $$ What mass of \(\mathrm{CaO}\), in grams, is needed to precipitate \(1000 \mathrm{lb}\) of \(\mathrm{Mg}(\mathrm{OH})_{2}\) ?
The dissociation energy of a carbon-bromine bond is typically about \(210 \mathrm{~kJ} / \mathrm{mol}\). (a) What is the maximum wavelength of photons that can cause C-Br bond dissociation? (b) Which kind of electromagnetic radiation-ultraviolet, visible, or infrared-does the wavelength you calculated in part (a) correspond to?
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