Chapter 12: Problem 17
(a) Draw a picture that represents a crystalline solid at the atomic level. (b) Now draw a picture that represents an amorphous solid at the atomic level.
Chapter 12: Problem 17
(a) Draw a picture that represents a crystalline solid at the atomic level. (b) Now draw a picture that represents an amorphous solid at the atomic level.
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Get started for freeWhich of the following statements does not follow from the fact that the alkali metals have relatively weak metal-metal bonding? (a) The alkali metals are less dense than other metals. (b) The alkali metals are soft enough to be cut with a knife. (c) The alkali metals are more reactive than other metals. (d) The alkali metals have higher melting points than other metals. (e) The alkali metals have low ionization energies.
At room temperature and pressure RbI crystallizes with the NaCl-type structure. (a) Use ionic radii to predict the length of the cubic unit cell edge. (b) Use this value to estimate the density. (c) At high pressure the structure transforms to one with a CsCl-type structure. (c) Use ionic radii to predict the length of the cubic unit cell edge for the highpressure form of RbI. (d) Use this value to estimate the density. How does this density compare with the density you calculated in part (b)?
State whether each sentence is true or false: (a) Metals have high electrical conductivities because the electrons in the metal are delocalized. (b) Metals have high electrical conductivities because they are denser than other solids. (c) Metals have large thermal conductivities because they expand when heated. (d) Metals have small thermal conductivities because the delocalized electrons cannot easily transfer the kinetic energy imparted to the metal from heat.
\(\mathrm{NaF}\) has the same structure as \(\mathrm{NaCl}\). (a) Use ionic radii from Chapter 7 to estimate the length of the unit cell edge for NaF. (b) Use the unit cell size calculated in part (a) to estimate the density of NaF.
Silicon is the fundamental component of integrated circuits. Si has the same structure as diamond. (a) Is Si a molecular, metallic, ionic, or covalent- network solid? (b) Silicon readily reacts to form silicon dioxide, \(\mathrm{SiO}_{2}\), which is quite hard and is insoluble in water. Is \(\mathrm{SiO}_{2}\) most likely a molecular, metallic, ionic, or covalent- network solid?
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