Chlorine dioxide gas \(\left(\mathrm{ClO}_{2}\right)\) is used as a commercial
bleaching agent. It bleaches materials by oxidizing them. In the course of
these reactions, the \(\mathrm{ClO}_{2}\) is itself reduced. (a) What is the
Lewis structure for \(\mathrm{ClO}_{2}\) ? (b) Why do you think that
\(\mathrm{ClO}_{2}\) is reduced so readily? (c) When a \(\mathrm{ClO}_{2}\)
molecule gains an electron, the chlorite ion, \(\mathrm{ClO}_{2}^{-}\), forms.
Draw the Lewis structure for \(\mathrm{ClO}_{2}^{-}\). (d) Predict the
\(\mathrm{O}-\mathrm{Cl}-\mathrm{O}\) bond angle in the
\(\mathrm{ClO}_{2}^{-}\)ion. (e) One method of preparing \(\mathrm{ClO}_{2}\) is
by the reaction of chlorine and sodium chlorite:
$$
\mathrm{Cl}_{2}(g)+2 \mathrm{NaClO}_{2}(s) \longrightarrow 2
\mathrm{ClO}_{2}(g)+2 \mathrm{NaCl}(s)
$$
If you allow \(15.0 \mathrm{~g}\) of \(\mathrm{NaClO}_{2}\) to react with \(2.00
\mathrm{~L}\) of chlorine gas at a pressure of \(1.50\) atm at \(21^{\circ}
\mathrm{C}\), how many grams of \(\mathrm{ClO}_{2}\) can be prepared?