Chapter 10: Problem 1
Mars has an average atmospheric pressure of \(0.007\) atm. Would it be easier or harder to drink from a straw on Mars than on Earth? Explain. [Section 10.2]
Chapter 10: Problem 1
Mars has an average atmospheric pressure of \(0.007\) atm. Would it be easier or harder to drink from a straw on Mars than on Earth? Explain. [Section 10.2]
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Get started for freeAcetylene gas, \(\mathrm{C}_{2} \mathrm{H}_{2}(g)\), can be prepared by the reaction of calcium carbide with water: $$ \mathrm{CaC}_{2}(s)+2 \mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{Ca}(\mathrm{OH})_{2}(a q)+\mathrm{C}_{2} \mathrm{H}_{2}(g) $$ Calculate the volume of \(\mathrm{C}_{2} \mathrm{H}_{2}\) that is collected over water at \(23{ }^{\circ} \mathrm{C}\) by reaction of \(1.524 \mathrm{~g}\) of \(\mathrm{CaC}_{2}\) if the total pressure of the gas is 753 torr. (The vapor pressure of water is tabulated in Appendix B.)
Briefly explain the significance of the constants \(a\) and \(b\) in the van der Waals equation.
When a large evacuated flask is filled with argon gas, its mass increases by \(3.224 \mathrm{~g}\). When the same flask is again evacuated and then filled with a gas of unknown molar mass, the mass increase is \(8.102 \mathrm{~g}\). (a) Based on the molar mass of argon, estimate the molar mass of the unknown gas. (b) What assumptions did you make in arriving at your answer?
Suppose you have two 1 -L flasks, one containing \(N_{2}\) at STP, the other containing \(\mathrm{CH}_{4}\) at STP. How do these systems compare with respect to (a) number of molecules, (b) density, (c) average kinetic energy of the molecules, (d) rate of effusion through a pinhole leak?
If \(5.15 \mathrm{~g}\) of \(\mathrm{Ag}_{2} \mathrm{O}\) is sealed in a 75.0-mL tube filled with 760 torr of \(\mathrm{N}_{2}\) gas at \(32^{\circ} \mathrm{C}\), and the tube is heated to \(320^{\circ} \mathrm{C}\), the \(\mathrm{Ag}_{2} \mathrm{O}\) decomposes to form oxygen and silver. What is the total pressure inside the tube assuming the volume of the tube remains constant?
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