Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
Chapter 18: Problem 67
What properties of CFCs make them ideal for various commercial applications but also make them a long-term problem in the stratosphere?
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Get started for freeThe precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\left(K_{s p}=1.3 \times 10^{-33}\right)\) is sometimes used to purify water. (a) Estimate the \(\mathrm{pH}\) at which precipitation of \(\mathrm{Al}(\mathrm{OH})_{3}\) will begin if \(5.0 \mathrm{lb}\) of \(\mathrm{Al}_{2}\left(\mathrm{SO}_{4}\right)_{3}\) is added to 2000 gal of water. (b) Approximately how many pounds of \(\mathrm{CaO}\) must be added to the water to achieve this \(\mathrm{pH}\) ?
Which choice is greener in a chemical process? Explain. (a) Benzene as a solvent or water as a solvent. (b) The reaction temperature is \(500 \mathrm{~K}\), or \(1000 \mathrm{~K}\). (c) Sodium chloride as a by-product or chloroform \(\left(\mathrm{CHCl}_{3}\right)\) as a by-product.
The Henry's law constant for \(\mathrm{CO}_{2}\) in water at \(25^{\circ} \mathrm{C}\) $$ \text { is } 3.1 \times 10^{-2} M \mathrm{~atm}^{-1} $$ (a) What is the solubility of \(\mathrm{CO}_{2}\) in water at this temperature if the solution is in contact with air at normal atmospheric pressure? (b) Assume that all of this \(\mathrm{CO}_{2}\) is in the form of \(\mathrm{H}_{2} \mathrm{CO}_{3}\) produced by the reaction between \(\mathrm{CO}_{2}\) and \(\mathrm{H}_{2} \mathrm{O}:\) $$ \mathrm{CO}_{2}(a q)+\mathrm{H}_{2} \mathrm{O}(l) \longrightarrow \mathrm{H}_{2} \mathrm{CO}_{3}(a q) $$ What is the \(\mathrm{pH}\) of this solution?
The following data were collected for the destruction of \(\mathrm{O}_{3}\) by \(\mathrm{H}\left(\mathrm{O}_{3}+\mathrm{H} \longrightarrow \mathrm{O}_{2}+\mathrm{OH}\right)\) at very low concentrations: $$ \begin{array}{llll} \hline \text { Trial } & {\left[\mathrm{O}_{3}\right](\boldsymbol{M})} & {[\mathrm{H}](\boldsymbol{M})} & \text { Initial Rate }(\boldsymbol{M} / \mathrm{s}) \\ \hline 1 & 5.17 \times 10^{-33} & 3.22 \times 10^{-26} & 1.88 \times 10^{-14} \\\ 2 & 2.59 \times 10^{-33} & 3.25 \times 10^{-26} & 9.44 \times 10^{-15} \\ 3 & 5.19 \times 10^{-33} & 6.46 \times 10^{-26} & 3.77 \times 10^{-14} \\ \hline \end{array} $$ (a) Write the rate law for the reaction. (b) Calculate the rate constant.
Air pollution in the Mexico City metropolitan area is among the worst in the world. The concentration of ozone in Mexico City has been measured at 441 ppb \((0.441\) ppm \()\). Mexico City sits at an altitude of 7400 feet, which means its atmospheric pressure is only 0.67 atm. (a) Calculate the partial pressure of ozone at 441 ppb if the atmospheric pressure is 0.67 atm. (b) How many ozone molecules are in \(1.0 \mathrm{~L}\) of air in Mexico City? Assume \(T=25^{\circ} \mathrm{C}\).
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