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A friend of yours has seen each of the following items in newspaper articles and would like an explanation: (a) acid rain, (b) greenhouse gas, \((\mathrm{c})\) photochemical smog, \((\mathbf{d})\) ozone depletion. Give a brief explanation of each term and identify one or two of the chemicals associated with each.

Short Answer

Expert verified
(a) Acid rain is a form of precipitation containing high levels of sulfuric and nitric acids, primarily caused by sulfur dioxide (SO₂) and nitrogen oxides (NOₓ) emissions. (b) Greenhouse gases, such as carbon dioxide (CO₂) and methane (CH₄), trap heat in the Earth's atmosphere, leading to the greenhouse effect and global warming. (c) Photochemical smog is air pollution resulting from chemical reactions between pollutants like nitrogen oxides (NOₓ) and volatile organic compounds (VOCs) in the presence of sunlight. (d) Ozone depletion refers to the reduction of ozone (O₃) in the Earth's stratosphere, primarily due to man-made chemicals like chlorofluorocarbons (CFCs) and halons, which leads to the thinning of the ozone layer and increased ultraviolet radiation reaching the Earth's surface.

Step by step solution

01

a) Acid Rain

Acid Rain is a form of precipitation with high levels of sulfuric and nitric acids, primarily resulting from the emission of sulfur dioxide (SO₂) and nitrogen oxides (NOₓ) from human activities, such as burning fossil fuels in power plants and vehicular emissions. These pollutants react with water, oxygen, and other chemicals present in the atmosphere, forming acidic compounds that fall back to Earth as rain, snow, fog, or dry particles. Acid rain can cause harm to ecosystems, including forests, lakes, and wildlife.
02

Associated Chemicals with Acid Rain

1. Sulfur Dioxide (SO₂) 2. Nitrogen Oxides (NOₓ)
03

b) Greenhouse Gas

Greenhouse gases are gases that trap heat in the Earth's atmosphere, leading to the greenhouse effect and global warming. The greenhouse effect is the warming that occurs when certain gases in the Earth's atmosphere trap heat. These gases let sunlight pass through the atmosphere but prevent heat from leaving the atmosphere, acting like a blanket that warms the Earth's surface. Major greenhouse gases include carbon dioxide (CO₂), methane (CH₄), nitrous oxide (N₂O), and fluorinated gases.
04

Associated Chemicals with Greenhouse Gas

1. Carbon Dioxide (CO₂) 2. Methane (CH₄)
05

c) Photochemical Smog

Photochemical smog is a type of air pollution that results from a complex series of chemical reactions between pollutants and sunlight. These reactions mainly involve nitrogen oxides (NOₓ) and volatile organic compounds (VOCs). When sunlight interacts with these pollutants, it forms ozone (O₃) and other harmful compounds. Photochemical smog consists of a mixture of ground-level ozone, particulate matter, and other chemicals. It is responsible for causing respiratory problems, eye irritation, reduced visibility, and damage to plants.
06

Associated Chemicals with Photochemical Smog

1. Nitrogen Oxides (NOₓ) 2. Volatile Organic Compounds (VOCs)
07

d) Ozone Depletion

Ozone depletion refers to the reduction of ozone (O₃) in the Earth's stratosphere, which is the layer of the atmosphere located between 10 to 50 kilometers above the Earth's surface. The ozone layer plays a vital role in filtering out harmful ultraviolet (UV) radiation from the Sun. One of the main causes of ozone depletion is the release of man-made chemicals, particularly chlorofluorocarbons (CFCs), which break down ozone molecules through chemical reactions, resulting in the thinning of the ozone layer.
08

Associated Chemicals with Ozone Depletion

1. Chlorofluorocarbons (CFCs) 2. Halons

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Acid Rain
Think of acid rain as nature's own chemistry experiment gone wrong. When we burn fuels like coal and oil, we release gases into the atmosphere that don't just vanish—they react. Specifically, sulfur dioxide (SO2) and nitrogen oxides (NOx) mix with atmospheric moisture, creating sulfuric and nitric acids. Unfortunately, the end result is acid rain, a type of precipitation that's more acidic than normal rainwater and can damage just about everything it touches—from forests and lakes to buildings and aquatic ecosystems. Imagine a subtle, corrosive rain that wears away at the very fabric of our delicate environment.

To visualize this easily, imagine a slice of bread (our environment) slowly getting drenched in vinegar (acid rain). Over time, just like the bread would disintegrate, so does our environment under the relentless drip of acid rain. And just like we might enjoy our bread with varied toppings, acid rain also contains a cocktail of harmful substances, but these are far from enjoyable: they include the main culprits we've mentioned, sulfur dioxide and nitrogen oxides.
Greenhouse Gases
In our atmosphere, there's a group of gases that act like a warm blanket—these are known as greenhouse gases. The most familiar ones include carbon dioxide (CO2), methane (CH4), and nitrous oxide (N2O). It's a natural and crucial effect, keeping our planet warm enough to be livable. However, there's such a thing as too much of a good thing. Our industrial activities, like burning fossil fuels and deforestation, are adding extra layers to this blanket, trapping more heat, and leading to global warming.

Consider a car parked in the sun with windows closed—a perfect example of the greenhouse effect. Just as the car gets hotter because the glass traps the sun's warmth, Earth heats up when excess greenhouse gases trap heat that would normally escape into space. This can lead to a variety of effects, including melting ice caps, rising sea levels, and extreme weather patterns.
Photochemical Smog
When the sun's rays become a key ingredient in pollution, we get what's known as photochemical smog. This smog forms when sunlight catalyzes chemical reactions between various pollutants in the atmosphere, mainly nitrogen oxides and volatile organic compounds—a recipe for a noxious mix of ozone and other harmful substances at ground level. Major cities with heavy traffic often find themselves veiled in this type of smog, which is not just an eyesore but also a health hazard, causing respiratory issues and impairing lung function.

An easy way to imagine this is to think of a light-activated pressure cooker filled with harmful gases. Under the intense energy of the sun, the cooker activates, transforming its ingredients into even more dangerous chemicals that seep into our urban environments. It's a clear sky that ironically ushers in the murkiness of photochemical smog, highlighting the complex relationship between human activity, air pollution, and solar radiation.
Ozone Depletion
High up in the stratosphere, there's a protective layer composed of ozone (O3) molecules, which safeguards our planet by absorbing most of the sun's harmful ultraviolet radiation. Unfortunately, this guardian—our ozone layer—is under attack. Certain chemicals, especially chlorofluorocarbons (CFCs), are like nefarious agents causing the ozone to break apart, which is known as ozone depletion. The consequences are dire: increased UV radiation reaching Earth's surface, leading to a higher incidence of skin cancer and cataracts, as well as adverse effects on plants and marine ecosystems.

To understand the importance of the ozone layer, imagine Earth without sunscreen. Just as sunscreen blocks harmful UV rays and protects our skin, the ozone layer prevents these rays from harming the diverse life forms on our planet. But when CFCs and other destructive chemicals wear down this natural sunscreen, not only does the risk to human health escalate, the very biological processes that sustain life on Earth are also threatened.

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Most popular questions from this chapter

The solar power striking Earth every day averages 168 watts per square meter. The peak electrical power usage in New York City is 12,000 megawatts. Considering that present technology for solar energy conversion is only about \(10 \%\) efficient, from how many square meters of land must sunlight be collected in order to provide this peak power? (For comparison, the total area of the city is \(830 \mathrm{~km}^{2}\).)

An important reaction in the formation of photochemical \(\operatorname{smog}\) is the photodissociation of \(\mathrm{NO}_{2}\) : $$ \mathrm{NO}_{2}+h \nu \longrightarrow \mathrm{NO}(g)+\mathrm{O}(g) $$ The maximum wavelength of light that can cause this reaction is \(420 \mathrm{nm} .\) (a) In what part of the electromagnetic spectrum is light with this wavelength found? (b) What is the maximum strength of a bond, in \(\mathrm{kJ} / \mathrm{mol}\), that can be broken by absorption of a photon of 420 -nm light? (c) Write out the photodissociation reaction showing Lewis-dot structures.

The first stage in corrosion of iron upon exposure to air is oxidation to \(\mathrm{Fe}^{2+}\). (a) Write a balanced chemical equation to show the reaction of iron with oxygen and protons from acid rain. (b) Would you expect the same sort of reaction to occur with a silver surface? Explain.

If the \(\mathrm{pH}\) of a 1.0 -in. rainfall over \(1500 \mathrm{mi}^{2}\) is 3.5 , how many kilograms of \(\mathrm{H}_{2} \mathrm{SO}_{4}\) are present, assuming that it is the only acid contributing to the \(\mathrm{pH}\) ?

(a) What is the difference between chlorofluorocarbons and hydrofluorocarbons? (b) Why are hydrofluorocarbons potentially less harmful to the ozone layer than CFCs?

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