Chapter 18: Problem 11
(a) What is the primary basis for the division of the atmosphere into different regions? (b) Name the regions of the atmosphere, indicating the altitude interval for each one.
Chapter 18: Problem 11
(a) What is the primary basis for the division of the atmosphere into different regions? (b) Name the regions of the atmosphere, indicating the altitude interval for each one.
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Get started for freeA reaction that contributes to the depletion of ozone in the stratosphere is the direct reaction of oxygen atoms with ozone: \(\mathrm{O}(g)+\mathrm{O}_{3}(g) \longrightarrow 2 \mathrm{O}_{2}(g)\) At \(298 \mathrm{~K}\) the rate constant for this reaction is \(4.8 \times 10^{5} \mathrm{M}^{-1} \mathrm{~s}^{-1}\). (a) Based on the units of the rate constant, write the likely rate law for this reaction. (b) Would you expect this reaction to occur via a single elementary process? Explain why or why not. (c) From the magnitude of the rate constant, would you expect the activation energy of this reaction to be large or small? Explain. (d) Use \(\Delta H_{f}^{\circ}\) values from Appendix \(\mathrm{C}\) to estimate the enthalpy change for this reaction. Would this reaction raise or lower the temperature of the stratosphere?
The average daily mass of \(\mathrm{O}_{2}\) taken up by sewage discharged in the United States is \(59 \mathrm{~g}\) per person. How many liters of water at \(9 \mathrm{ppm} \mathrm{O}_{2}\) are totally depleted of oxygen in 1 day by a population of 1,200,000 people?
The degradation of \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) (an HFC) by OH radicals in the troposphere is first order in each reactant and has a rate constant of \(k=1.6 \times 10^{8} \mathrm{M}^{-1} \mathrm{~s}^{-1}\) at \(4{ }^{\circ} \mathrm{C}\). If the tropo- spheric concentrations of \(\mathrm{OH}\) and \(\mathrm{CF}_{3} \mathrm{CH}_{2} \mathrm{~F}\) are \(8.1 \times 10^{5}\) and \(6.3 \times 10^{8}\) molecules/cm \(^{3}\), respectively, what is the rate of reaction at this temperature in \(M / s ?\)
Which choice is greener in a chemical process? Explain. (a) A reaction that can be run at \(350 \mathrm{~K}\) for 12 hours without a catalyst or one that can be run at \(300 \mathrm{~K}\) for 1 hour with a catalyst. (b) A reagent for the reaction that can be obtained from corn husks or one that can be obtained from petroleum. (c) \(\mathrm{A}\) process that produces no by-products or one in which the byproducts are recycled for another process.
It has been pointed out that there may be increased amounts of \(\mathrm{NO}\) in the troposphere as compared with the past because of massive use of nitrogen-containing compounds in fertilizers. Assuming that NO can eventually diffuse into the stratosphere, how might it affect the conditions of life on Earth? Using the index to this text, look up the chemistry of nitrogen oxides. What chemical pathways might \(\mathrm{NO}\) in the troposphere follow?
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