Chapter 11: Problem 86
A watch with a liquid crystal display (LCD) does not function properly when it is exposed to low temperatures during a trip to Antarctica. Explain why the LCD might not function well at low temperature.
Chapter 11: Problem 86
A watch with a liquid crystal display (LCD) does not function properly when it is exposed to low temperatures during a trip to Antarctica. Explain why the LCD might not function well at low temperature.
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Get started for freeWhich type of intermolecular force accounts for each of these differences: (a) \(\mathrm{CH}_{3} \mathrm{OH}\) boils at \(65^{\circ} \mathrm{C} ; \mathrm{CH}_{3} \mathrm{SH}\) boils at \(6^{\circ} \mathrm{C}\). (b) Xe is liquid at atmospheric pressure and \(120 \mathrm{~K}\), whereas \(\mathrm{Ar}\) is a gas under the same conditions. (c) \(\mathrm{Kr}\), atomic weight 84 , boils at \(120.9 \mathrm{~K},\) whereas \(\mathrm{Cl}_{2},\) molecular weight about \(71,\) boils at \(238 \mathrm{~K}\). (d) Acetone boils at \(56^{\circ} \mathrm{C}\), whereas 2 -methylpropane boils at \(-12^{\circ} \mathrm{C}\)
(a) What atoms must a molecule contain to participate in hydrogen bonding with other molecules of the same kind? (b) Which of the following molecules can form hydrogen bonds with other molecules of the same kind: \(\mathrm{CH}_{3} \mathrm{~F}, \mathrm{CH}_{3} \mathrm{NH}_{2}\), \(\mathrm{CH}_{3} \mathrm{OH}, \mathrm{CH}_{3} \mathrm{Br} ?\)
The critical temperatures \((\mathrm{K})\) and pressures \((\mathrm{atm})\) of a series of halogenated methanes are as follows: $$ \begin{array}{lcccc} \text { Compound } & \mathbf{C C l}_{3} \mathbf{F} & \mathbf{C C l}_{2} \mathbf{F}_{2} & \mathbf{C C I F}_{3} & \mathbf{C F}_{4} \\ \hline \text { Critical temperature } & 471 & 385 & 302 & 227 \\ \text { Critical pressure } & 43.5 & 40.6 & 38.2 & 37.0 \end{array} $$ (a) List the intermolecular forces that occur for each compound. (b) Predict the order of increasing intermolecular attraction, from least to most, for this series of compounds. (c) Predict the critical temperature and pressure for \(\mathrm{CCl}_{4}\) based on the trends in this table. Look up the experimentally determined critical temperatures and pressures for \(\mathrm{CCl}_{4}\), using a source such as the CRC Handbook of Chemistry and Physics, and suggest a reason for any discrepancies.
Which type of intermolecular attractive force operates between (a) all molecules, (b) polar molecules, (c) the hydrogen atom of a polar bond and a nearby small electronegative atom?
Ethylene glycol \(\left(\mathrm{HOCH}_{2} \mathrm{CH}_{2} \mathrm{OH}\right),\) the major substance in antifreeze, has a normal boiling point of \(198^{\circ} \mathrm{C} .\) By comparison, ethyl alcohol \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}\right)\) boils at \(78^{\circ} \mathrm{C}\) at atmospheric pressure. Ethylene glycol dimethyl ether \(\left(\mathrm{CH}_{3} \mathrm{OCH}_{2} \mathrm{CH}_{2} \mathrm{OCH}_{3}\right)\) has a normal boiling point of \(83^{\circ} \mathrm{C}\), and ethyl methyl ether \(\left(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OCH}_{3}\right)\) has a normal boiling point of \(11^{\circ} \mathrm{C}\). (a) \(\mathrm{Ex}-\) plain why replacement of a hydrogen on the oxygen by a \(\mathrm{CH}_{3}\) group generally results in a lower boiling point. (b) What are the major factors responsible for the difference in boiling points of the two ethers?
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