Chapter 14: Problem 23
What is osmosis? What is osmotic pressure?
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Key Concepts
These are the key concepts you need to understand to accurately answer the question.
Chapter 14: Problem 23
What is osmosis? What is osmotic pressure?
These are the key concepts you need to understand to accurately answer the question.
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A solution of methanol and water has a mole fraction of water of 0.312 and a total vapor pressure of 211 torr at \(39.9^{\circ} \mathrm{C}\) . The vapor pressures of pure methanol and pure water at this temperature are 256 torr and 55.3 torr, respectively. Is the solution ideal? If not, what can you say about the relative strengths of the solute-solvent interactions compared to the solute-solute and solvent-solvent interactions?
Some laboratory procedures involving oxygen-sensitive reactants or products call for using water that has been boiled (and then cooled). Explain.
A 0.100 \(\mathrm{M}\) ionic solution has an osmotic pressure of 8.3 \(\mathrm{atm}\) at \(25^{\circ} \mathrm{C}\) .Calculate the van't Hoff factor \((i)\) for this solution.
Sodium hydroxide \((\mathrm{NaOH})\) has a lattice energy of \(-887 \mathrm{k} / \mathrm{k} / \mathrm{mol}\) and a heat of hydration of \(-932 \mathrm{k} / \mathrm{mol}\) . How much solution could be heatcd to boiling by the heat cvolved by the dissolution of 25.0 \(\mathrm{g}\) of \(\mathrm{NaOH}\) ? (For the solution, assume a heat capacity of \(4.0 \mathrm{J} / \mathrm{g} \cdot^{\circ} \mathrm{C},\) an initial temperature of \(25.0^{\circ} \mathrm{C},\) a boiling point of \(100.0^{\circ} \mathrm{C},\) and a density of 1.05 \(\mathrm{g} / \mathrm{mL} . )\)
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