Question

What is sublimation? Cite a common example of sublimation.

Short answer

Sublimation is the transition of a substance directly from solid to gas. A common example is the sublimation of dry ice into CO2 gas.

Step-by-step solution

Define Sublimation

Sublimation refers to the process where a substance changes directly from a solid to a gas without passing through the liquid state. This phase transition occurs under specific temperature and pressure conditions.

Provide a Common Example

A well-known example of sublimation is the transition of dry ice, which is solid carbon dioxide (CO2), directly into carbon dioxide gas when it is at room temperature or when exposed to air.

Key concepts

Phase Transition

A phase transition is a process where a substance changes its state of matter, such as going from solid to liquid, liquid to gas, or vice versa. One lesser-known transition, which is particularly fascinating, is sublimation. Here, a solid changes directly into a gas without first becoming a liquid. This can occur under specific conditions of temperature and pressure, often in situations where heat increases or pressure decreases, giving the particles enough energy to break free of their solid structure and directly enter the gaseous state.

Understanding phase transitions involves a bit of thermodynamics. The temperature acts as a source of energy for particles within a substance. When a solid reaches its sublimation point, the particles gain enough kinetic energy that their vibrational motion overcomes the forces holding them together in a solid arrangement. Instead of moving into a fluid liquid state, these particles escape directly into the air as gas. Sublimation is an endothermic process, meaning it absorbs heat from its environment, which is why sublimating substances often feel cold to the touch.

Dry Ice

Dry ice, the solid form of carbon dioxide (CO2), is the most common example of sublimation that many people encounter. Unlike water ice, which melts into a liquid before it becomes a gas, dry ice sublimates directly from a solid to a gas at temperatures above -78.5 degrees Celsius (-109.3 degrees Fahrenheit), a process that happens even at room temperature.

Dry ice offers practical applications due to its sublimation properties. It's used for keeping things cold without the mess of a liquid melt, it's a tool for flash-freezing food, and it even creates that eerie fog effect in theatrical productions and haunted houses. Because it changes directly to a gas, it dissipates into the air leaving no residue. This makes dry ice a unique refrigerant, especially in situations where water from melted ice could cause problems. However, ventilation is important where dry ice is used because as it sublimates, it increases the carbon dioxide level in the air, which can be dangerous in enclosed spaces.

Solid to Gas

The transition from solid to gas, or sublimation, isn't just a fascinating scientific fact; it also provides a great insight into the dynamic nature of particles within substances. At the molecular level, this phase change is all about the energy and spacing of particles. Solids have particles that are tightly packed together with only a little bit of wiggle room, which is what keeps them rigid.

As you increase the temperature—think of it as giving energy to the particles—they start to wiggle more violently. When they wiggle enough, and if the surrounding pressure is low, they can break free entirely, leaping into the space as a gas. This process bypasses the liquid phase entirely. It's a testament to the delicate balance of forces acting at the microscopic level and how changes in temperature and pressure can dramatically alter the physical state of a substance.