Chapter 7: Problem 24
The oxalate ion, \(\mathrm{C}_{2} \mathrm{O}_{4}^{2-},\) has the skeleton
structure
Chapter 7: Problem 24
The oxalate ion, \(\mathrm{C}_{2} \mathrm{O}_{4}^{2-},\) has the skeleton
structure
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Get started for freeDraw the Lewis structure and describe the geometry of the hydrazine molecule, \(\mathrm{N}_{2} \mathrm{H}_{4} .\) Would you expect this molecule to be polar?
Phosphoryl chloride, \(\mathrm{POCl}_{3}\), has the skeleton structure Write (a) a Lewis structure for \(\mathrm{POCl}_{3}\) following the octet rule. Calculate the formal charges in this structure. (b) a Lewis structure in which all the formal charges are zero. (The octet rule need not be followed.)
It is possible to write a simple Lewis structure for the \(\mathrm{SO}_{4}^{2-}\) ion, involving only single bonds, which follows the octet rule. However, Linus Pauling and others have suggested an alternative structure, involving double bonds, in which the sulfur atom is surrounded by six electron pairs. (a) Draw the two Lewis structures. (b) What geometries are predicted for the two structures? (c) What is the hybridization of sulfur in each case? (d) What are the formal charges of the atoms in the two structures?
Borazine, \(\mathrm{B}_{3} \mathrm{~N}_{3} \mathrm{H}_{6},\) has the skeleton Draw the resonance forms of the molecule.
In each of the following molecules, a central atom is surrounded by a total of three atoms or unshared electron pairs: \(\mathrm{SnCl}_{2}, \mathrm{BCl}_{3}, \mathrm{SO}_{2} .\) In which of these molecules would you expect the bond angle to be less than \(120^{\circ}\) ? Explain your reasoning.
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